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Which of the following is not a reasonable retrosynthesis? Rr Longrightarrow Longrightarrow
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- provide the retrosynthesis for the following кон HOOnly one of these statements about nucleophilic aromatic substitution is true. O as the number of ortho and para electron withdrawing groups increases, the reaction rate decreases O the reaction proceeds by an addition-elimination mechanism the reaction involves a carbocation intermediate with delocalization of electrons all are falseWhen fumarate reacts with D2O in the presence of the enzyme fumarase, only one isomer of the product is formed, as shown here. Is the enzyme catalyzing a syn or an anti addition of D2O?
- Which of the following would be the product of the reaction sequence shown? 1. NaCr203 2. CH3MGB.Othesis. teps neceossary to synthesize this compound by yl halide; after that you can add any organic or Dound. →1-hexanol )Consider the following compounds: B = HOCH2CH2CH2CH3 CH3 HC C = CH3CH2CH2OCH2CH2CH3 D = a) Which one(s) could be reduced with NaBH4? b) Which one(s) would give a positive Tollens silver mirror test? c) Which one(s) could be oxidized with CrO3? d) Which one(s) would react with 1 or 2 equivalents CH3M9B to make a npound butyl ethyl ether larger alcohol?3) Please draw the structures that correspond to omitted structure for each of the following synthetic sequences. HO Cro3 Cro3 (a) Product `OH Product H,0 HO PCC Cl РСС (b) Product (e) Product OH HO РСС NABHA (f) Starting Material (c) Product OH ELOH
- Give the major organic product or missing starting material for the following reaction do either letter. Please explain the process/mechanismProvide the mechanism for the following reactions.Fluoride ion is usually a poor leaving group because it is not very polarizable. Fluorideserves as the leaving group in the Sanger reagent (2,4-dinitrofluorobenzene), used inthe determination of peptide structures (Chapter 24). Explain why fluoride works as aleaving group in this nucleophilic aromatic substitution, even though it is a poor leavinggroup in the SN1 and SN2 mechanisms.