Which of the following is true of O2 2- ? it has a bond order of 2 It is diamagnetic It is paramagnetic it has more antibonding electrons than bonding electrons it is heteronuclear

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter9: Covalent Bonding: Orbitals
Section: Chapter Questions
Problem 5RQ: Electrons in bonding molecular orbitals are most likely to be found in the region between the two...
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Which of the following is true of O2 2- ?

it has a bond order of 2

It is diamagnetic

It is paramagnetic

it has more antibonding electrons than bonding electrons

it is heteronuclear 

Expert Solution
Step 1

According to the molecular orbital theory, the atomic orbitals combine to forms molecular orbitals. The number of molecular orbitals is equal to the number of atomic orbitals. Half of the molecular orbitals have lower energy than the atomic orbitals, these molecular orbitals are known as the bonding molecular orbitals (BMO). And the remaining half of molecular orbitals have an energy higher than the atomic orbital, these molecular orbitals are known as the antibonding molecular orbital (ABMO).

Step 2

The molecular orbital diagram of O22- is as follows:

Chemistry homework question answer, step 2, image 1

Step 3

bond order=(number of electrons in bonding orbitals-number of electrons in antibonding orbitals)2

bond order=6-42

bond order=1

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