• Which of the following radicals is expected to be the least selective? 1. HO• 2. F. 3. Cl• 4. Br• 5. I. • How many constitutional monochloride isomers will form in the radical-chain chlorination of 2,3- dimethylpentane? 1. 3 2. 4 3. 4. 6 5. 7 Which mechanistic step decides the regiochemistry of the radical-chain chlorination of 2-methylpropane?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter15: Radical Reactions
Section: Chapter Questions
Problem 11E
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• Which of the following radicals is expected to be the
least selective?
1.
HO•
2.
F•
3.
Cl•
4.
Br•
5.
I•
• How many constitutional monochloride isomers will
form in the radical-chain chlorination of 2,3-
dimethylpentane?
1.
3
2.
3.
5
4.
5.
7
Which mechanistic step decides the regiochemistry of
the radical-chain chlorination of 2-methylpropane?
1. Protonation step
Hydrogen abstraction step
Chlorine abstraction step
2.
3.
4.
Chloride addition step
5.
Initiation step
Transcribed Image Text:• Which of the following radicals is expected to be the least selective? 1. HO• 2. F• 3. Cl• 4. Br• 5. I• • How many constitutional monochloride isomers will form in the radical-chain chlorination of 2,3- dimethylpentane? 1. 3 2. 3. 5 4. 5. 7 Which mechanistic step decides the regiochemistry of the radical-chain chlorination of 2-methylpropane? 1. Protonation step Hydrogen abstraction step Chlorine abstraction step 2. 3. 4. Chloride addition step 5. Initiation step
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