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- . Compatible Polymers A and B are to be blended to achieve a glass-transition temperatureof 60 oC. Tg’s of Polymers A and B are 30 and 85 oC, respectively, using an appropriateequation determine the composition of the blend.Comelli and Francesconi examined mixtures of propionic acid with various other organic liquids at 313.15 K (F. Comelli and R. Francesconi, J. Chem. Eng. Data 41, 101 (1996)). They report the excess volume of mixing propionic acid with tetrahydropyran (THP, oxane) as VE = x1x2{a0 + a1(x1 − x2)}, where x1 is the mole fraction of propionic acid, x2 that of THP, a0 = −2.4697 cm3 mol−1, and a1 = 0.0608 cm3 mol−1. The density of propionic acid at this temperature is 0.971 74 g cm−3; that of THP is 0.863 98 g cm−3. (a) Derive an expression for the partial molar volume of each component at this temperature. (b) Compute the partial molar volume for each component in an equimolar mixture.Phase equilibria data for the system water / acetone / trichloroethane phase equilibria data for the coexisting phases in mole% extract phase raffinate phase trichloroethane| acetone | water (trichloroethane| acetone water 80,18 o 0,07 59,01 . ) 0,10
- Extintion coeficient for Y is 1280What is ΔSsys for a freezing phase transition at 29.7 °C for a compound that freezes at 29.7 °C and the ΔHsys = -19.45 kJ mol-1 for this process? Express your answer in J mol-1 K-1 to at least two significant figures.The freezing-point of depression of a 0.010 b acetic acid solution is 0.00193 K. Calculate thedegree of dissociation for acetic acid at this concentration. Cryoscopic constant for the aceticacid is 1.86 K mol kg mol-1.
- Solid Na2S is slowly added to a solution of 1.0 x 10-3 M Cr3+ (with no change in volume). At what [S2-] will Cr2S3 start to ppt? For Cr2S3, Ksp = 1.0 x 10-20Chloroform (1)/methyl ethyl ketone (2) form a solution in vapor liquid equilibrium at 330 K. The chloroform concentration in the liquid phase is x1 = 0.55. Assuming an ideal gas and an ideal solutionof liquids, what are y1 and P (in kPa), to 3 significant figures?In lecture I mentioned that standard state is usually at 25oC; however, it can be at any specified temperature. In problems 9 and 10 you will calculate ΔGo from Ksp data. The Ksp range over the temperature range in these two problems is consistent with some actual solubility data; however, in order to allow each student to do their own calculation I have made this data for an "unknown" ionic solid. Calculate the value of ΔGo (kJ/mol) at 3.3oC for the dissolution of an ionic solid with a Ksp of 2.5 x 10-11 at 3.3oC. Your answer should have 2 sig figs.
- 1 At a temperature of 302.8 K, mixtures of phenol andwater exist as two separate phases with mole fractionsof phenol of 0.30 and 0.93. Use the lever rule to determine the relative amounts of the two phases for amixture w ith an overall mole fraction of phenol of 0.45.The following evidence was obtained from an experiment to determine the solubility of calcium chloride at room temperature. A sample of saturated calcium chloride solution was evaporated to dryness, and the mass of solid residue was measured.EvidenceVolume of solution (mL) = 15.0Mass of empty beaker (g) = 90.54Mass of beaker and residue (g) = 101.36The solubility of calcium chloride is g/100 mLA liquid-vapour mixture whose composition is 60 mole % of benzene is contained within a vessel at 60C. What fraction of moles are both methanol and in the liquid phase?