Why can an atom with a singlet spin multiplicity (S=0) have no spin-spin coupling with any other atom?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.56E
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2. Why can an atom with a singlet spin multiplicity (S=0) have no spin-spin coupling with any other atom?
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