Why do we expect electron transitions deep within an atomto produce shorter wavelengths than transitions by outerelectrons?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter5: Quantum Mechanics And Atomic Structure
Section: Chapter Questions
Problem 44AP: The energy needed to ionize an atom of element X when it is in its most stable state is 500kJmol1 ....
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Why do we expect electron transitions deep within an atom
to produce shorter wavelengths than transitions by outer
electrons?

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