Why is [Cr(NH3)6]3+ more stable than [Cr(PH3)6]3+ ?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section20.7: Crystal-field Theory: Color And Magnetism In Coordination Compounds
Problem 20.13CE
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Why is [Cr(NH3)6]3+ more stable than [Cr(PH3)6]3+ ?

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Step 1

Here the central metal ion is the same in both the coordination compounds which is Cr3+.

But the ligand is different in both the coordination compounds.

The ligand is NH3 in [Cr(NH3)6]3+, and PH3 in [Cr(PH3)6]3+

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