a) Draw the structure and the systematic name of the following d-metal complexes: (0) [Mn(CO),H₂] (II) [Ti(CşHs),Cl] (iii) [Cr(CO)(PPha)]

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 105QRT
icon
Related questions
Question
ds/CHE3701_2022_TL_101_0_B.pdf
C
Question 1
a)
b)
a)
Question 2
X
$
4
(i) [Mn(CO)3H3]
(ii) [Ti(C5H5)2Cl2]
(iii) [Cr(CO)5(PPh3)]
(iv) [Mo(n-C6H6)(C₂H4)2]
Draw the structure and the systematic name of the following d-metal complexes:
(i)
[Mn(CO)3H3]
(ii)
[Ti(C5H5)2Cl2]
(iii) [Cr(CO)5(PPh3)]
(iv) [Mo(nº-C8H6)(C₂H4)2]
(v) [Fe2(CO)9]
Give the d-electron count (use the neutral ligand counting method) of the following
complexes:
R
[Fe₂(CO)9]
F
A compound with empirical formula Fe2(C5H5)2(CO)4 exhibits carbonyl stretching
frequencies at 1780 and 2000 cm³¹. Draw the structure of the compound and assign the
v(CO) stretches in the structure.
OLO
C
F5
%
5
-
G
F6
+
Y
a
X
****
F7
&
7
H
9
U
N
* CO
8
J
AV-
D
W
F9
F10
K
V
F11
Transcribed Image Text:ds/CHE3701_2022_TL_101_0_B.pdf C Question 1 a) b) a) Question 2 X $ 4 (i) [Mn(CO)3H3] (ii) [Ti(C5H5)2Cl2] (iii) [Cr(CO)5(PPh3)] (iv) [Mo(n-C6H6)(C₂H4)2] Draw the structure and the systematic name of the following d-metal complexes: (i) [Mn(CO)3H3] (ii) [Ti(C5H5)2Cl2] (iii) [Cr(CO)5(PPh3)] (iv) [Mo(nº-C8H6)(C₂H4)2] (v) [Fe2(CO)9] Give the d-electron count (use the neutral ligand counting method) of the following complexes: R [Fe₂(CO)9] F A compound with empirical formula Fe2(C5H5)2(CO)4 exhibits carbonyl stretching frequencies at 1780 and 2000 cm³¹. Draw the structure of the compound and assign the v(CO) stretches in the structure. OLO C F5 % 5 - G F6 + Y a X **** F7 & 7 H 9 U N * CO 8 J AV- D W F9 F10 K V F11
Expert Solution
steps

Step by step

Solved in 2 steps with 3 images

Blurred answer
Knowledge Booster
Atomic Structure and Spectra
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781133611097
Author:
Steven S. Zumdahl
Publisher:
Cengage Learning