Answered: why is the formation of an amide from…

why is the formation of an amide from an acid chloride proceeds easily when appropriate amount of amine is added to the reaction but an amide to an acid chloride is impossible

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter23: Addition To A Carbonyl

Section: Chapter Questions

Problem 25E

See similar textbooks

Related questions

Q: What is the acidity and PKA value of each compound? Explain in detail, please. А. OH O "I OCH 3 B.…

A: The compounds which can easily release protons in the solution are called acids, while the compounds…

Q: Write the equilibrium constant expressions for Kc and Kp, if applicable, for the following…

Q: Write the nuclear equations for the following radioactive processes: A parent undergoes beta decay…

A: Given that A parent undergoes beta decay and produces osmium-193. The nuclear equations for the…

Q: The value of the entropy change for the process CaBr₂ (s) --> Ca²⁺ (aq) + 2Br ⁻ (aq) is __________.…

A: Entropy - It is the measure of randomness or disorder of a system, more randomness more entropy of…

Q: What would be the ¹4C activity in a 2500-year old wooden object? Assume that the ¹4C activity of an…

Q: If 28.5 g of NaOH is added to 0.800 L of 1.00 M Zn(NO₃)₂, what mass in grams of Zn(OH)₂ will be…

A: Given data mass of NaOH = 28.5 g volume of Zn(NO3)2 = 0.800 L molarity of Zn(NO3)2 = 1.00 M Reaction…

Q: Assume that you are conducting a chain-addition polymerization using 5.15 grams of monomer (MW=…

A: We need to find the expected number of repeat units per chain. Masses of monemers are given. This…

Q: What quantity in moles of precipitate will be formed when 102.0 mL of 0.200 M NaBr is reacted with…

Q: 5. (a) Draw the product/s of the reaction; (b) Indicate the mechanism: changed from acetone to…

A: Here we are required to find the product of the reaction.

Q: A student has a solution of sodium nitrate and believes it is saturated. Which statement provides…

A: Solutions are liquids that contain dissolved substances inside, usually former solids. Dissolving…

Q: 5. A typical aspirin tablet contains 325mg of acetylsalicylic acid (HC9H704) which is a weak acid.…

A: Aspirin is having carboxylic group which is a weak acid and partially dissociates into its…

Q: A voltaic cell using Pb²+/Pb and Ni²+/Ni half-cells is set up at standard conditions, and each…

A: Here we have to determine the Ecell of the following given standard galvanic cell after passing 0.15…

Q: How will you separate the components of the following mixtures? Suggest a method and describe it.…

A: Mixtures can be separated using differences in physical properties to separate the components. The…

Q: Using the table of standard formation enthalpies that you'll find under the ALEKS Data tab,…

A: Since, The standard enthalpy of the formation is defined as change of enthalpy of 1 mol of the…

Q: are the breakdown fragmentation pathways of 4-methoxyphenyl acetate

A: The mass spectrum of 4-methoxyphenyl acetate can be illustrated by the following: Initially, there…

Q: Select the answer from the choices. Cell Reaction: Cu(s) + 2H+ ↔ Cu2+ + H2(g) Eºcell= +0.340…

Q: Determine why these reagents wouldn't work to form the product given using the same starting…

Q: How many grams of Co are there in a sample of Co that contains 8.40×1023 atoms? grams

A: The solution to the given problem is as follows:

Q: Sketch a graph for the solubility of potassium nitrate and cerium sulfate in water as a function of…

A: We need to construct a graph for the solubility of (a) potassium nitrate and (b) cerium sulfate in…

Q: What mass of precipitate (in g) is formed when 20.5 mL of 0.500 M Cu(NO3)2 reacts with 20.0 mL of…

A: Here we are required to find the mass of precipitate formed during the given reaction 1L=1000 ml.

Q: Liquid sodium sulfate reacts with carbon monoxide(g) to form liquid sodium sulfide and carbon…

A: ΔHr = ΣniΔHf(Product) - ΣniΔHf(Reactant) where, ΔHr is Heat or Enthalpy of reaction, ni and ΔHf are…

Q: what is the product of 1-Hexyne reacting with 1 equivalent of HBr? Include E/Z if necessary.

A: We have to give the product of the reaction of 1-hexyne with 1 equivalent of HBr. Introduction:…

Q: How many bonding electrons are in a molecule of HFCCFH?

A: Chemical bond: A chemical bond is formed by two electrons between the two atoms. So, a single bond…

Q: If you were given 21mg of CH3Hg, how many atoms of hydrogen are there

A: Since, Moles is the ratio of mass to the molar mass of that atom or molecules. Also, Number of atoms…

Q: In this reaction: Mg (s) + I₂ (s) → MgI₂ (s) If 2.90 moles of Mg react with 3.56 moles of I₂, and…

A: Given, Reaction: Mg (s) + I₂ (s) → MgI₂ (s) Moles of Mg= 2.90 moles Moles of I2 = 3.56 moles Moles…

Q: (I pn Ph hv сия, вст

A: when light falls photochemical reaction take place

Q: A sample of polystyrene, which has a specific heat capacity of 1.880J·g−1·°C−1 , is put into a…

Q: What is the solubility of Mg(OH)₂ at a pH of 13.00? (Ksp Mg(OH)₂ is 1.6 × 10⁻¹³)

Q: Classify the following reaction: H₂SO₄(aq) + Fe(s) → H₂(g) + FeSO₄(aq) A) synthesis (or combination)…

Q: a) b) c) d) OH H₂C=N=N OH + 0₂ осно + N=N

A: a) benzene1-2 oxide isomerise to phenol. In nature cytochrome P450 hydroxylyse to form phenol. b)…

Q: - + 8 O = red F = green Write a balanced chemical equation for this reaction, using the smallest…

A: Given, Red balls = O Green balls = F

Q: PbCl2 is a slightly soluble salt. A solution contains 0.0045 M Pb+2. What concentration of Cl- is…

A: Concept based on the solubility product and ionic product of the sparingly soluble salt. If Ionic…

Q: 10.49 (...) Synthesize the following molecules beginning with only organic molecules containing…

A: Disclamer :- According to the bartleby guidelines for the multipart questions. I can solve only…

Q: give the IUPAC name

A: For IUPAC nomenclature of alkenes, the longest hydrocarbon chain carrying double bond is taken as a…

Q: Given Ka CH3COOH=1.8x10-5; Kb NH3=1.8x10-5 Which solution has the highest pH? a. 0.1 M CH3COOH b.…

A: Given that Ka of CH3COOH = 1.0 × 10-5 and Kb of NH3 = 1.0 × 10-5 Among the 0.1 M solution of…

Q: Figure A and Figure B represent examples of different types of chemical bonding. Identify the…

A: Ionic bond: These bonds are formed by the transfer of electrons from one atom to another. Covalent…

Q: if you perform QC for sodium on a chemistry analyzer and the value is greater than 2SD above the…

A: The value of QC for sodium on a chemistry analyzer has been >2SD for that analyte on the second…

Q: What product(s) are expected in the ethoxide-promoted β‑elimination reaction of…

A: Given reaction is elimination reaction. Ethoxide act as base. HCl is eliminated.

Q: 1) Pretend there is a new metal dogium with the symbol D, and it is a variable charge metal. It…

A: Oxide is written as O2- having the charge of -2 and phosphate is written as PO43- having the charge…

Q: 2. An aqueous solution of NH, has a pH of 11.6. The ammonia (NH) molecule is the conjugate base of…

A: Since you have asked multiple questions and the first question you posted is incomplete, we will…

Q: Br N=N=N i Add the missing curved arrow notation. + 8 :Br:

A: Benzyl bromide undergoes biomolecular nucleophilic substitution when treated with azide ion( N3-)…

Q: If a gaseous mixture is made by combining 3.64 g Ar and 3.55 g Kr in an evacuated 2.50 L container…

Q: Starting with the following equation, Fe₂O₃(s) + Al(s) → Fe(l) + Al₂O₃(s) calculate the moles of…

Q: Acetic acid, sold as vinegar, is produced by the carbonylation of methanol, according to the…

Q: A sample of krypton gas occupies 5.00 L at 4.89 atm. What volume does the gas occupy at 10.4 atm?…

A: We are to discuss which gas law gives the relation between pressure and volume. also, we have V1 =…

Q: Given the following information at 25°C, Calculate AH° for the combustion of methane, CH4, according…

A: The standard enthalpy of formation is the enthalpy change of reaction in standard conditions when…

Q: b) Write a full electron configuration of 82Pb, and a shortham Atom: 1s 2s 2p 3s 3p 3d 1 st ion:…

A: Since, Electronic configuration represent the electron present in orbital in which way. Arrangement…

Q: Calculate the standard entropy changes for the following reaction: MgCO3(s) ---> MgO(s) + CO2(g)…

Q: give the IUPAC name for the compound

Q: The combustion of octane, C8H18,C8⁢H18, proceeds according to the reaction shown.…

Question

why is the formation of an amide from an acid chloride proceeds easily when appropriate amount of amine is added to the reaction but an amide to an acid chloride is impossible

Definition Definition Organic compounds with a nitrogen atom having a lone pair of electrons on it. Amines are derived from ammonia (NH 3 ), wherein hydrogen atoms are substituted by an aryl or alkyl group.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1Concept

VIEW

Step 2 Explanation

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

please explain the reaction and mechanism of sulfide to sulfimide and from sulfimide to allylic amine
When acetophenone, hydroxelamine hydrochloride, and sodium hydroxide are reacted to synthesize acetophenone oxime, why is it necessary to add hydrochloric acid after the reaction to make it acidic?
Why does p-nitroacetanilide recrystallize in ethanol, but the o-acetanilide remains in the filtrate during amide synthesis( the synthesis of p-nitroacetanilide).
We saw that it is necessary to use excess amine in the reaction of an acyl chloride with an amine. Explain why it is not necessary to use excess alcohol in the reaction of an acyl chloride with an alcohol.
An alternative procedure for preparing the amine of Step 3 is reductive amination of the corresponding ketone. What is reductive amination? Why might this two-step route for formation of the amine be preferred over the one-step reductive amination?
¨ Aspirin is an ester and undergoes the typical reaction of esters. Write a mechanism for the reaction. Taking this in mind, why should you not recrystallize aspirin from hot water?
Write the step by step mechanism with curved arrows of the hydrolysis of the amide in this reaction.
Write the mechanism for a reaction of a SECONDARY AMINE with an ACID CHLORIDE to generate an AMIDE and HCl.
Show the reaction mechanisms in converting benzophenone to benzopinacol to benzopinacolone. Why must the mixture of benzophenone and isopropyl alcohol with acid be exposed to sunlight? Suppose that the flask is coated with sunscreen, would the reaction work?
The reaction that occurs when the benzaldehyde you have is reacted in a basic environment is called the Cannizzaro reaction, and when it is reacted with cyanide, it is called benzoin. It Explain the reason by writing the reaction mechanisms of the reactions.
Benzenesulfonyl chloride or p-toluenesulfonylchloride give N-substituted sulfonamides with primary and secondary amines. The derivative consisting of primary amines is insoluble in dilute NaOH. Is that true or false?
please help with this question. thank you. n-acetylazoles go through hydrolysis more than regular amides. propose a reason for the reactivity of n-acetylazoles toward nucleophilic substitution.