Why was HCl added to the unknown sulfate solution before adding the BaCl2 solution?

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter15: Solubility And Complex Lon Equilibria
Section: Chapter Questions
Problem 77AE: A solution contains 0.018 mole each of I, Br, and Cl. When the solution is mixed with 200. mL of...
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a. Why was HCl added to the unknown sulfate solution before adding the BaCl2 solution? 

b. Suppose that a small portion of the sulfate precipitated as lead sulfate rather than as barium sulfate. How would this change the result of the analysis? 

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