Please take a look to see if I'm on the right track with my thinking thank you for your time. S212141MODEL AscentMAKE SlaboraYEAR 2011BODY TQteningSESEMyPhysical/Chemical Properties:HM(6H14a.1. For the compound drawn, answer the following:What is the geometry around each carbon atom?b. What is the bond angle around each carbon atom?C.d.2. For the compound:a.What is the hybridization of each carbon atom? (sp, sp² or sp³Is the compound soluble or insoluble in water?doneBeadCN HLAFZ)C&H 18C-HHH-CH3CH₂ CH3CSH12Tetraned cal109.5HCS H 12HJoctaneWhat is the geometry for the carbon atoms attached to the double bond?trig ona.--Hi-HHb.What is the bond angle for the carbon atoms attached to the double bond?120c.What is the hybridization of each carbon atom attached to the double bond?(sp, sp² or sp³)SP3d. Would the melting point for this compound be higher or lower than that of analcohol?HigherDrawing Organic Structures:1. In the space provided draw the condensed formula for the molecular formula: C3H8Condensed formula:Hin Soluble inwater8*8=16+2 = 18planong? (double bord)L-C+2. State if the following compounds are constitutional isomers or different compounds.2-methylhexane & 3,3-dimethylpentaneConstitutional isomers or different compounds: Constitutional IsumersDraw structures for both compounds below:S WES4. Based on Zaitsev's rule, write the major/minor products, as well as the side product, forthe following dehydration reaction of alcohols and label the major product.OHmajorFirst indicate the classification of alcohol (primary, secondary or tertiary), then using theclassification, draw the aldehyde, ketone, carboxylic acid or no product formed whenthe following alcohols are mildly oxidized. *keep in mind there is a byproduct of water inmost oxidation reactions1.तं तं लं2.3.a.4.b.H₂SO4180°CH1.H-H H OHC-C-HH H HoptCH3-CH-CH3Classify the alcohol: 1°, 2° or 3⁰OHClassify the alcohol: 1°, 2° or 3⁰6. In the following structure, list all 7 of the functional groups present.O2.J3.minorAldehydeetherAlkeneAromatic[0]D__1°4.[0]Aldehydes.5.сCH3-11|||20C-CH3 +₂00HS5.?H3C-CH2-CH2-OH-OCH3-CH2-CH6.OH7.OHthiolAlcohol6.7. Carboxylic acid

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YEAR 2021 we Slabora MODEL Ascent Thizis Physical/Chemical Properties: 1. For the compound drawn, answer the following: a. What is the geometry around each carbon atom? b. What is the bond angle around each carbon atom? C. d. C5H12 tetrand cal 109.5 1 in Soluble inwater 8$$=16 +2 = 18 What is the hybridization of each carbon atom? (sp, sp² of sp Is the compound soluble or insoluble in water? done • Bond CN H₂n+2) GEHIE

YEAR 2021 we Slabora MODEL Ascent Thizis Physical/Chemical Properties: 1. For the compound drawn, answer the following: a. What is the geometry around each carbon atom? b. What is the bond angle around each carbon atom? C. d. C5H12 tetrand cal 109.5 1 in Soluble inwater 8$$=16 +2 = 18 What is the hybridization of each carbon atom? (sp, sp² of sp Is the compound soluble or insoluble in water? done • Bond CN H₂n+2) GEHIE

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter10: Molecular Structure And Bonding Theories

Section: Chapter Questions

Problem 10.99QE: The molecular orbital diagram of NO shown in Figure 10.47 also applies to the following species....

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Which of the following molecules or ions are para-magnetic? What is the highest occupied molecular orbital (HOMO) in each one? Assume the molecular orbital diagram in Figure 9.16 applies to all of them. (a) NO (b) OF (c) O22 (d) Ne2+
The organic compound below is a member of a class known as oximes. (a) What are the hybridizations of the two C atoms and of the N atom? (b) What is the approximate CNO angle?
If we replace the hydrogen atoms in ammonia with the ethyl moieties (C2H5)3— N),there is no change in the hybridization of central oxygen atom, yet they have differentbond angles, Why? Which molecule has lower bond angle? Give reasons to supportyour answer.(d) What is the simplest justifications for believing that molecular structure is more oftengoverned by BP-BP/BP-LP/LP-LP repulsions than by the van der Walls repulsions ofthe nonbonding electrons on the substituent atoms? (e)Explain the influence of physical state and designing of metal on metallic corrosion.
Draw a 3D representation of the molecule ketene, H2C=C=O, using the following EXPLICIT instructions: sigma bonds in the plane of the paper are normal lines, sigma bonds or orbitals projecting in front of the page are heavy lines, sigma bonds or orbitals projecting behind the page are dashed lines, and pi bonds are shown by drawing the lobes of the p-orbitals and indicating the overlaps. What is the hybridization of each atom (except H) in this molecule?
What are the bond angles around heteroatoms and non-sp3 hybridised C atoms in C14H23NO ?
1. Calculate the percentage s and p characters in sp, sp^2 and sp^3 hybrid orbitals. 2. Draw the molecular orbital diagram of propene, CH3-CH=CH2. 3. Draw an orbital diagram of an allene, H2C=C=CH2. What hybridization must the central carbon atom have in order to form two double bonds? 4. Describe the shape of sp^3 hybrid orbitals. 5. Dicuss, with illustrations, the two main steps in the hybridization of a carbon atom. 6.a. Arrange the following organic molecules in order of increasing acidity, starting with the least acidic. CH3CH3, HC(=_)CH and CH2=CH2 b. How many hybrid orbitals are formed when one 2s atomic orbital mixes with two 2p atomic orbitals? What shape do they form? c. Describe in detail, the shape of p atomic orbitals. d. Giving an example, explain what is meant by the excited-state electronic configuration of an atom of an element. e. Using clear illustrations, discuss the main differences between E1 and E2 mechanisms in organic reactions.
1a)Identify the molecules below that contains 2-sigma bonding orbitals and 2-pi bonding orbitals? why? a. ethane b. methanol c.ethene d. carbon dioxide 1b) What of the following polyatomic ions contains the fewest valence electrons? why? a. Chlorate b. Chlorite c. hypochlorite d. bicrabonate
a) Consider a molecule of acetone cyanohydrin, shown below. What is the hybridization and molecular geometry at CA, CB, and O? (b) For Carbon B (CB) and nitrogen (N), draw orbital energy diagrams showing the orbitals involved in bonding after hybridization. Be sure to fill the orbitals appropriately with valence electrons. c) In your diagrams in part (b), which orbitals are involved in sigma and pi bonding? Orbitals Involved in Sigma Bonding Orbitals Involved in Pi Bonding 2p sp sp2 sp3 2p sp sp2 sp3 (d) In a sample containing many molecules of acetone cyanohydrin (and no other substances), what type(s) of intermolecular forces could be present? Choose all that apply. Covalent Bonds Hydrogen Bonds Dipole-Dipole Forces London Dispersion Forces
Part A) What is the molar concentration of sodium ions in an aqueous solution prepared by dissolving 3.00 g of sodium sulfate in 2.50 L of solution? (a) 0.00845 M (b) 0.0169 M (c) 1.20 M (d) 0.0211 M Part B) What is the hybridization state of nitrogen atom in ammonia? (a) sp (b) sp2 (c) sp3 (d) sp3d (e) sp3d2 Part c) Name the following compound: FePO4 Part D) Chemical formula of manganese (III) sulfate is: (a) MgSO3 (b) MnSO4 (c) MgS (d) Mn2(SO4)3 (e) Mn2S3 4) Chemical formula of potassium sulfide is (a) P2S3 (b) K2SO3 (c) PtS (d) K2S (e) K2SO4
Q.8(a)Write the MO electronic configuration of diatomic molecule having a bond order of three. If the electron pair following a bond between 2 atoms A and B is not in the center. Then what kind of bond is formed? (b) Although the outermost electronic configuration of transition elements is ns1 or ns2 like alkali and alkaline earth metal still they are not reactive like group 1 and 2 elements why it is so? (c) What is molar conductance, equivalent conductance and specific conductance? How they are interrelated? Discuss on each type of conductance effect of dilution with graph.
1. a) Draw the dominant Lewis structure for the allene molecule (1,2-propyl diene, CH2CCH2 ) and use VSEPR theory to determine the molecule's geometry. In specifying the geometry give all bond angles and specify which nuclei lie in the same plane. b) Propose a hybridization and bonding scheme for the atoms in allene. That is, specify how each of the atoms is hybridized, which atomic orbitals overlap to form bonding molecular orbitals, and the nature (i.e., 0", 7f, etc.) of these molecular orbitals. c) Draw a plausible valence molecular orbital level diagram for allene (include only bonding MOs) based on the results from (b). d) Based on the work from (c) deduce the valence electronic configuration of the ground state of allene. e) Is the molecule planar or nonplanar? Explain your answer
1. a) Draw the dominant Lewis structure for the allene molecule (1,2-propyl diene, CH2CCH2 ) and use VSEPR theory to determine the molecule's geometry. In specifying the geometry give all bond angles and specify which nuclei lie in the same plane. b) Propose a hybridization and bonding scheme for the atoms in allene. That is, specify how each of the atoms is hybridized, which atomic orbitals overlap to form bonding molecular orbitals, and the nature (i.e., sigma", pi, etc.) of these molecular orbitals. c) Draw a plausible valence molecular orbital level diagram for allene (include only bonding MOs) based on the results from (b). d) Based on the work from (c) deduce the valence electronic configuration of the ground state of allene. e) Is the molecule planar or nonplanar? Explain your answer Answer subparts c, d, and e