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Introductory Chemistry: A Foundation

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter17: Equilibrium

Section: Chapter Questions

Problem 5CR

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Question 4
Which of the following would react most rapidly?
a. A lump of Zn in 1.0 M HCI at 40° C
Ob. Powdered Zn in 2.0 M HCI at 40° C
Oc. lump of Zn in 2.0 M HCI at 25° C
Od. Powdered Zn in 1.0 M HCI at 25° C
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How is the strength of an acid related to the position of its ionization equilibrium? Write the equations for the dissociation (ionization) of HCI, HNO3, and HClO4in water. Since all these acids are strong acids, what does this indicate about the basicity of the Cl-, NO3, and ClO4ions? Are aqueous solutions of NaCl, NaNO3, or NaClO4basic?
Which of the following will affect the total amount of solute that can dissolve in a given amount of solvent? a. The solution is stirred. b. The solute is ground to fine particles before dissolving. c. The temperature changes.
How many grams of Milk of Magnesia, Mg(OH)2 (s) (58.3 g/mol), would be soluble in 200 mL of water. (KSP=7.11012). Include the ionic reaction and the expression for Ksp, in your answer. (Kw=11014=[H3O+][HO]).
. Lead(II) chloride, PbCl2(s), dissolves in water to the extent of approximately 3.6102Mat 20 °C. Calculate Kspfor PbCl2(s), and calculate its solubility in grams per liter.
Calculate the equilibrium concentrations that result when 0.25 M O2 and 1.0 M HCl react and come to equilibrium. 4HCl(g)+O2(g)2Cl2+2H2O(g)Kc=3.11013
. Under what circumstances can we compare the solubilities of two salts by directly comparing the values of their solubility products?
For the following reactions, predict whether the pressure of the reactants or products increases or remains the same when the volume of the reaction vessel is increased. (a) H2O(l)H2O(g) (b) N2(g)+3H2(g)2NH3(g) (c) C2H4(g)+H2O(g)C2H5OH(g)
. The solubility product of iron(III) hydroxide is very small: Ksp=41038at 25 °C. A classical method of analysis for unknown samples containing iron is to add NaOH or NH3. This precipitates Fe(OH)3, which can then be filtered and weighed. To demonstrate that the concentration of iron remaining in solution in such a sample is very small, calculate the solubility of Fe(OH)3in moles per liter and in grams per liter.
Part3: Based on your ICE table and equilibrium expression Kb, determine the initial moles of NaClO added to this solution.
Solid aluminum phosphate and solid aluminum hydroxide are in equilibrium with a solution containing 6.54x10^-3 M potassium phosphate. Calculate the concentration of hydroxide ion present in this solution. [hydroxide] = ????? M
PbCrO4 is a common pigment called chrome yellow (or school bus yellow). It has a solubility of 1.71 x 10-4 g/L. The solubility product of PbCrO4, Ksp = ________. Enter the result in scientific notation to 1 decimal. e.g. enter 5.6x10-5 as 5.6E-5.
I had 1.0 mL of 1.0M CoCl2 in a test tube. I put it into boiling water. [Co(H2O)6]2+, [CoCl4]2- Equilibrium temperature effect. Effect of heat What happens to the equilibrium? Use this equation in your explanation... 4Cl_ (aq) + [Co(H20)6]2+(aq)---[CoCl4]2-(aq)+ 6 H20 (l) I did this in class. The color change was very slow but it changed from a burgandy to fushia.

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