The reaction (CH3)3CBr + OH-→ (CH3)3COH + Br- in a certain solvent is first order with respect to (CH3)3CBr and zero order with respect to OH-. In several experiments, the rate constant k was determined at different temperatures. A plot of ln(k) versus 1/T was constructed resulting in a straight line with a slope value of -1.10 × 104 K and yintercept of 33.5. Assume k has units of s-1. a. Determine the activation energy for this reaction. b. Determine the value of the frequency factor A. c. Calculate the value of k at 25°C.
The reaction (CH3)3CBr + OH-→ (CH3)3COH + Br- in a certain solvent is first order with respect to (CH3)3CBr and zero order with respect to OH-. In several experiments, the rate constant k was determined at different temperatures. A plot of ln(k) versus 1/T was constructed resulting in a straight line with a slope value of -1.10 × 104 K and yintercept of 33.5. Assume k has units of s-1. a. Determine the activation energy for this reaction. b. Determine the value of the frequency factor A. c. Calculate the value of k at 25°C.
Chemistry for Engineering Students
3rd Edition
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.52PAE
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6- The reaction (CH3)3CBr + OH-→ (CH3)3COH + Br- in a certain solvent is first order with respect to (CH3)3CBr and zero order with respect to OH-. In several experiments, the rate constant k was determined at different temperatures. A plot of ln(k) versus 1/T was constructed resulting in a straight line with a slope value of -1.10 × 104 K and yintercept of 33.5. Assume k has units of s-1. a. Determine the activation energy for this reaction. b. Determine the value of the frequency factor A. c. Calculate the value of k at 25°C.
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