For the past 10 years, the unsaturated hydrocarbon 1,3-butadiene (CH2 = CH – CH = CH,) has ranked 38th among the top 50 industrial chemicals. It is used primarily for the manufacture of synthetic rubber. An isomer exists also as cyclobutene: CH,- CH, CH =CH The isomerization of cyclobutene to butadiene is first-order and the rate constant has been measured as 2.0 x 10-4 s1 at 150 °C in a 0.53-L flask. Determine the partial pressure of cyclobutene and its concentration after 30.0 minutes if an isomerization reaction is carried out at 150 °C with an initial pressure of 55 torr.

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 50E: For the past 10 years, the unsaturated hydrocarbon 1, 3-butadiene (CH2 = CH - CH = CH2) has ranked...
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For the past 10 years, the unsaturated hydrocarbon 1,3-butadiene (CH2 = CH – CH = CH,) has ranked 38th
among the top 50 industrial chemicals. It is used primarily for the manufacture of synthetic rubber. An isomer exists
also as cyclobutene:
CH,- CH,
CH =CH
The isomerization of cyclobutene to butadiene is first-order and the rate constant has been measured as 2.0 x 10-4
s1 at 150 °C in a 0.53-L flask. Determine the partial pressure of cyclobutene and its concentration after 30.0
minutes if an isomerization reaction is carried out at 150 °C with an initial pressure of 55 torr.
Transcribed Image Text:For the past 10 years, the unsaturated hydrocarbon 1,3-butadiene (CH2 = CH – CH = CH,) has ranked 38th among the top 50 industrial chemicals. It is used primarily for the manufacture of synthetic rubber. An isomer exists also as cyclobutene: CH,- CH, CH =CH The isomerization of cyclobutene to butadiene is first-order and the rate constant has been measured as 2.0 x 10-4 s1 at 150 °C in a 0.53-L flask. Determine the partial pressure of cyclobutene and its concentration after 30.0 minutes if an isomerization reaction is carried out at 150 °C with an initial pressure of 55 torr.
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