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ChemistryChemistry9th Edition

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Chapter 12, Problem 62E
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Chemistry

9th Edition
Steven S. Zumdahl
ISBN: 9781133611097

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Chemistry

9th Edition
Steven S. Zumdahl
ISBN: 9781133611097
Textbook Problem

The mechanism for the gas-phase reaction of nitrogen dioxide with carbon monoxide to form nitric oxide and carbon dioxide is thought to be

NO 2   +   NO 2   →   NO 3   +   NO         S l o w NO 3   +   CO   →   NO 2   +   CO 2           F a s t

Write the rate law expected for this mechanism. What is the overall balanced equation for the reaction?

Interpretation Introduction

Interpretation: A proposed mechanism of gas-phase reaction of nitrogen dioxide is given. The rate law and overall balanced equation for the reaction is to be determined.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.

To determine: The rate law of the given reaction.

Explanation

The slow step of reaction mechanism is rate determining step. In the given mechanism of a reaction, first step is slow step. Hence, it is a rate determining step.

The proposed first step mechanism is,

NO2+NO2→NO3+NO

The rate law gives the relation between reaction rate and concentration of reactants. The given reaction consists of two reactants, that is, NO2 . Hence, the rate law for the given reaction is,

Rate=k[NO2][NO2]=k[NO2]2

Where,

  • k is rate constant.
  • [NO2] is concentration of reactant.

To determine: The overall balanced equation of the given reaction

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Ch-12 P-11RQCh-12 P-1ALQCh-12 P-2ALQCh-12 P-3ALQCh-12 P-4ALQCh-12 P-5ALQCh-12 P-6ALQCh-12 P-7ALQCh-12 P-8ALQCh-12 P-9ALQCh-12 P-10QCh-12 P-11QCh-12 P-12QCh-12 P-13QCh-12 P-14QCh-12 P-15QCh-12 P-16QCh-12 P-17QCh-12 P-18QCh-12 P-19QCh-12 P-20QCh-12 P-21QCh-12 P-22QCh-12 P-23ECh-12 P-24ECh-12 P-25ECh-12 P-26ECh-12 P-27ECh-12 P-28ECh-12 P-29ECh-12 P-30ECh-12 P-31ECh-12 P-32ECh-12 P-33ECh-12 P-34ECh-12 P-35ECh-12 P-36ECh-12 P-37ECh-12 P-38ECh-12 P-39ECh-12 P-40ECh-12 P-41ECh-12 P-42ECh-12 P-43ECh-12 P-44ECh-12 P-45ECh-12 P-46ECh-12 P-47ECh-12 P-48ECh-12 P-49ECh-12 P-50ECh-12 P-51ECh-12 P-52ECh-12 P-53ECh-12 P-54ECh-12 P-55ECh-12 P-56ECh-12 P-57ECh-12 P-58ECh-12 P-59ECh-12 P-60ECh-12 P-61ECh-12 P-62ECh-12 P-63AECh-12 P-64AECh-12 P-65AECh-12 P-66AECh-12 P-67AECh-12 P-68AECh-12 P-69AECh-12 P-70AECh-12 P-71AECh-12 P-72AECh-12 P-73AECh-12 P-74AECh-12 P-75AECh-12 P-76AECh-12 P-77AECh-12 P-78AECh-12 P-79AECh-12 P-80AECh-12 P-81AECh-12 P-82AECh-12 P-83AECh-12 P-84AECh-12 P-85AECh-12 P-86AECh-12 P-87AECh-12 P-88AECh-12 P-89AECh-12 P-90AECh-12 P-91AECh-12 P-92AECh-12 P-93AECh-12 P-94CWPCh-12 P-95CWPCh-12 P-96CWPCh-12 P-97CWPCh-12 P-98CWPCh-12 P-99CWPCh-12 P-100CWPCh-12 P-101CWPCh-12 P-102CPCh-12 P-103CPCh-12 P-104CPCh-12 P-105CPCh-12 P-106CPCh-12 P-107CPCh-12 P-108CPCh-12 P-109CPCh-12 P-110CPCh-12 P-111CPCh-12 P-112CPCh-12 P-113IPCh-12 P-114IPCh-12 P-115IPCh-12 P-116MP

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