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ChemistryChemistry: An Atoms First Approach2nd Edition
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Place the species in each of the following groups in order of increasing base strength. Give your reasoning in each case. a. IO 3 − , BrO 3 − b. NO 2 − ,NO 3 − c. OCl − , OI −

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Chemistry: An Atoms First Approach

2nd Edition
Steven S. Zumdahl + 1 other
Publisher: Cengage Learning
ISBN: 9781305079243

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Chemistry: An Atoms First Approach

2nd Edition
Steven S. Zumdahl + 1 other
Publisher: Cengage Learning
ISBN: 9781305079243
Chapter 13, Problem 132E
Textbook Problem
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Place the species in each of the following groups in order of increasing base strength. Give your reasoning in each case.

a. IO3−, BrO3−

b. NO2−,NO3−

c. OCl−, OI−

(a)

Interpretation Introduction

Interpretation: The species in the given groups are to be placed in the order of increasing base strength.

Concept introduction: The species left when an acid compound donates a proton in a chemical reaction is known as a conjugate base.

The conjugate acid of a stronger acid is a weaker base.

To determine: The correct order of increasing base strength.

Explanation of Solution

Explanation

In case of HIO3 , the central atom present is iodine (I) that is more electronegative than the central atom present in HBrO3 , that is bromine (Br) . The acidic strength of a compound increases as the electronegativity value of its central atom increases.

Therefore, the correct order of increasing acidic strength is, HBrO3<HIO3

(b)

Interpretation Introduction

Interpretation: The species in the given groups are to be placed in the order of increasing base strength.

Concept introduction: The species left when an acid compound donates a proton in a chemical reaction is known as a conjugate base.

The conjugate acid of a stronger acid is a weaker base.

To determine: The correct order of increasing base strength.

(c)

Interpretation Introduction

Interpretation: The species in the given groups are to be placed in the order of increasing base strength.

Concept introduction: The species left when an acid compound donates a proton in a chemical reaction is known as a conjugate base.

The conjugate acid of a stronger acid is a weaker base.

To determine: The correct order of increasing base strength.

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