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ChemistryChemistry & Chemical ReactivityA titration of 25.0 mL of a solution of the weak base aniline, C 6 H 5 NH 2 , requires 25.67 mL of 0.175 M HCl to reach the equivalence point. C 6 H 5 NH 2 (aq) + H 3 O + (aq) ⇄ C 6 H 5 NH 3 + (aq) + H 2 O( ℓ ) (a) What was the concentration of aniline in the original solution? (b) What are the concentrations of H 3 O + , OH − , and C 6 H 5 NH 3 + at the equivalence point? (c) What is the pH of the solution at the equivalence point?
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A titration of 25.0 mL of a solution of the weak base aniline, C 6 H 5 NH 2 , requires 25.67 mL of 0.175 M HCl to reach the equivalence point. C 6 H 5 NH 2 (aq) + H 3 O + (aq) ⇄ C 6 H 5 NH 3 + (aq) + H 2 O( ℓ ) (a) What was the concentration of aniline in the original solution? (b) What are the concentrations of H 3 O + , OH − , and C 6 H 5 NH 3 + at the equivalence point? (c) What is the pH of the solution at the equivalence point?

BuyFind

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
Publisher: Cengage Learning
ISBN: 9781337399074
BuyFind

Chemistry & Chemical Reactivity

10th Edition
John C. Kotz + 3 others
Publisher: Cengage Learning
ISBN: 9781337399074

Solutions

Chapter
Section
Problem 1PS
Problem 2PS
Problem 3PS
Problem 4PS
Problem 5PS
Problem 6PS
Problem 7PS
Problem 8PS
Problem 9PS
Problem 10PS
Problem 11PS
Problem 12PS
Problem 13PS
Problem 14PS
Problem 15PS
Problem 16PS
Problem 17PS
Problem 18PS
Problem 19PS
Problem 20PS
Problem 21PS
Problem 22PS
Problem 23PS
Problem 24PS
Problem 25PS
Problem 26PS
Problem 27PS
Problem 28PS
Problem 29PS
Problem 30PS
Problem 31PS
Problem 32PS
Problem 33PS
Problem 35PS
Problem 36PS
Problem 37PS
Problem 38PS
Problem 39PS
Problem 40PS
Problem 41PS
Problem 42PS
Problem 43PS
Problem 44PS
Problem 45PS
Problem 46PS
Problem 47PS
Problem 48PS
Problem 49PS
Problem 50PS
Problem 51PS
Problem 52PS
Problem 53PS
Problem 54PS
Problem 55PS
Problem 56PS
Problem 57PS
Problem 58PS
Problem 59PS
Problem 60PS
Problem 61PS
Problem 62PS
Problem 63PS
Problem 64PS
Problem 65PS
Problem 66PS
Problem 67PS
Problem 68PS
Problem 69PS
Problem 70PS
Problem 71PS
Problem 72PS
Problem 73PS
Problem 74PS
Problem 75PS
Problem 76PS
Problem 77GQ
Problem 78GQ
Problem 79GQ
Problem 80GQ
Problem 81GQ
Problem 82GQ
Problem 83GQ
Problem 84GQ
Problem 85GQ
Problem 86GQ
Problem 87GQ
Problem 88GQ
Problem 89GQ
Problem 90GQ
Problem 91GQ
Problem 92GQ
Problem 93GQ
Problem 94GQ
Problem 95GQ
Problem 96GQ
Problem 97GQ
Problem 98GQ
Problem 99GQ
Problem 100GQ
Problem 101IL
Problem 102IL
Problem 103IL
Problem 104IL
Problem 105IL
Problem 106IL
Problem 107IL
Problem 108IL
Problem 109IL
Problem 110IL
Problem 111IL
Problem 112IL
Problem 113SCQ
Problem 114SCQ
Problem 115SCQ
Problem 116SCQ
Problem 117SCQ
Problem 118SCQ
Problem 119SCQ
Problem 120SCQ
Chapter 17, Problem 30PS
Textbook Problem

A titration of 25.0 mL of a solution of the weak base aniline, C6H5NH2, requires 25.67 mL of 0.175 M HCl to reach the equivalence point.

C6H5NH2(aq) + H3O+(aq) ⇄ C6H5NH3+(aq) + H2O(ℓ)

(a) What was the concentration of aniline in the original solution?

(b) What are the concentrations of H3O+, OH−, and C6H5NH3+ at the equivalence point?

(c) What is the pH of the solution at the equivalence point?

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Chapter 17 Solutions

Chemistry & Chemical Reactivity
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Ch. 17.1 - You have a 0.30 M solution of formic acid (HCO2H)...Ch. 17.2 - What is the pH of a buffer solution composed of...Ch. 17.2 - Use the Henderson-Hasselbalch equation to...Ch. 17.2 - Using an acetic acid/sodium acetate buffer...Ch. 17.2 - Calculate the pH of 0.500 L of a buffer solution...Ch. 17.3 - The titration of 0.100 M acetic acid with 0.100 M...Ch. 17.3 - Calculate the pH after 75.0 mL of 0.100 M HO has...Ch. 17.4 - The barium ion concentration, [Ba2+], in a...Ch. 17.4 - Calculate the solubility of AgCN in moles per...Ch. 17.4 - Calculate the solubility of Ca(OH)2 in moles per...Ch. 17.4 - Calculate the solubility of BaSO4 (a) in pure...Ch. 17.5 - Solid Pbl2 (Ksp = 9.8 109) is placed in a beaker...Ch. 17.5 - What is the minimum concentration of I that can...Ch. 17.5 - You have 100.0 mL of 0.0010 M silver nitrate. Will...Ch. 17.6 - Silver nitrate (0.0050 mol) is added to 1.00 L of...Ch. 17.6 - Calculate the value of the equilibrium constant,...Ch. 17.6 - Approximately 0.10 g of sodium cyanide is fatal to...Ch. 17.6 - What is the minimum volume of 0.0071 M NaCN(aq)...Ch. 17.6 - Use the formation constant of [Au(CN)2] in...Ch. 17.6 - Silver undergoes similar reactions as those shown...Ch. 17.6 - Write a balanced chemical equation for the...Ch. 17.6 - Phosphate ions are abundant in cells, both as the...Ch. 17.6 - A typical total phosphate concentration in a cell,...Ch. 17 - Does the pH of the solution increase, decrease or...Ch. 17 - Does the pH of the solution increase, decrease, or...Ch. 17 - What is the pH of a solution that consists of 0.20...Ch. 17 - What is the pH of 0.15 M acetic acid to which 1.56...Ch. 17 - What is the pH of the solution that results from...Ch. 17 - What is the pH of the solution that results from...Ch. 17 - What is the pH of the buffer solution that...Ch. 17 - Lactic acid (CH3CHOHCO2H) is found in sour milk,...Ch. 17 - What mass of sodium acetate, NaCH3CO2, must he...Ch. 17 - What mass of ammonium chloride, NH4Cl, must be...Ch. 17 - Calculate the pH of a solution that has an acetic...Ch. 17 - Calculate the pH of a solution that has an...Ch. 17 - What must the ratio of acetic acid to acetate ion...Ch. 17 - What must the ratio of H2PO4 to HPO42 be to have a...Ch. 17 - A buffer is composed of formic acid and its...Ch. 17 - A buffer solution is composed of 1.360 g of KH2PO4...Ch. 17 - Which of the following combinations would be the...Ch. 17 - Which of the following combinations would be the...Ch. 17 - Describe how to prepare a buffer solution from...Ch. 17 - Describe how to prepare a buffer solution from NH3...Ch. 17 - Determine the volume (in mL) of 1.00 M NaOH that...Ch. 17 - Determine the volume (in mL) of 1.00 M HC1 that...Ch. 17 - A buffer solution was prepared by adding 4.95 g of...Ch. 17 - You dissolve 0.425 g of NaOH in 2.00 L of a buffer...Ch. 17 - A buffer solution is prepared by adding 0.125 mol...Ch. 17 - What is the pH change when 20.0 mL of 0.100 M NaOH...Ch. 17 - Phenol, C6H5OH, is a weak organic acid. Suppose...Ch. 17 - Assume you dissolve 0.235 g of the weak acid...Ch. 17 - You require 36.78 mL of 0.0105 M HCl to reach the...Ch. 17 - A titration of 25.0 mL of a solution of the weak...Ch. 17 - Without doing detailed calculations, sketch the...Ch. 17 - Without doing detailed calculations, sketch the...Ch. 17 - You titrate 25.0 mL of 0.10 M NH3 with 0.10 M HCl....Ch. 17 - Using Figure 17.11, suggest an indicator to use in...Ch. 17 - Using Figure 17.11, suggest an indicator to use in...Ch. 17 - Name two insoluble salts of each of the following...Ch. 17 - Name two insoluble salts of each of the following...Ch. 17 - Using the solubility guidelines (Figure 3.10),...Ch. 17 - Predict whether each of the fallowing is insoluble...Ch. 17 - For each of the following insoluble salts, (1)...Ch. 17 - For each of the following insoluble salts, (1)...Ch. 17 - When 1.55 g of solid thallium(I) bromide is added...Ch. 17 - At 20 C, a saturated aqueous solution of silver...Ch. 17 - When 250 mg of SrF2, strontium fluoride, is added...Ch. 17 - Calcium hydroxide, Ca(OH)2, dissolves in water to...Ch. 17 - You add 0.979 g of Pb(OH)2 to 1.00 L of pure water...Ch. 17 - You place 1.234 g of solid Ca(OH)2 in 1.00 L of...Ch. 17 - Estimate the solubility of silver iodide in pure...Ch. 17 - What is the molar concentration of Au+(aq) in a...Ch. 17 - Estimate the solubility of calcium fluoride, CaF2,...Ch. 17 - Estimate the solubility of lead(II) bromide (a) in...Ch. 17 - The Ksp value for radium sulfate, RaSO4, is 4.2 ...Ch. 17 - If 55 mg of lead(II) sulfate is placed in 250 mL...Ch. 17 - Use Ksp values to decide which compound in each of...Ch. 17 - Use Ksp values to decide which compound in each of...Ch. 17 - Calculate the molar solubility of silver...Ch. 17 - Calculate the solubility of silver bromide, AgBr,...Ch. 17 - Compare the solubility, in milligrams per...Ch. 17 - What is the solubility, in milligrams per...Ch. 17 - Calculate the solubility, in moles per liter, of...Ch. 17 - Calculate the solubility, in moles per liter, of...Ch. 17 - Which insoluble compound in each pair should be...Ch. 17 - Which compound in each pair is more soluble in...Ch. 17 - You have a solution that has a lead(II) ion...Ch. 17 - Sodium carbonate is added to a solution in which...Ch. 17 - If the concentration of Zn2+ in 10.0 mL of water...Ch. 17 - You have 95 mL of a solution that has a lead(II)...Ch. 17 - If the concentration of Mg2+ ion in seawater is...Ch. 17 - Will a precipitate of Mg(OH)2 form when 25.0 mL of...Ch. 17 - Zinc hydroxide is amphoteric (Section 16.10). Use...Ch. 17 - Solid silver iodide, AgI, can be dissolved by...Ch. 17 - What amount of ammonia (moles) must be added to...Ch. 17 - Can you dissolve 15.0 mg of AuCl in 100.0 mL of...Ch. 17 - What is the solubility of AgCl (a) in pure water...Ch. 17 - The chemistry of silver(I) cyanide: (a) Calculate...Ch. 17 - In each of the following cases, decide whether a...Ch. 17 - In each of the following cases, decide whether a...Ch. 17 - If you mix 48 mL of 0.0012 M BaCl2 with 24 mL of...Ch. 17 - Calculate the hydronium ion concentration and the...Ch. 17 - Calculate the hydronium ion concentration and the...Ch. 17 - For each of the following cases, decide whether...Ch. 17 - Rank the following compounds in order of...Ch. 17 - A sample of hard water contains about 2.0 103 M...Ch. 17 - What is the pH of a buffer solution prepared from...Ch. 17 - If you place 5.0 mg of SrSO4 in 1.0 L of pure...Ch. 17 - Describe the effect on the pH of the following...Ch. 17 - What volume of 0.120 M NaOH must be added to 100....Ch. 17 - A buffer solution is prepared by dissolving 1.50 g...Ch. 17 - What volume of 0.200 M HCl must be added to 500.0...Ch. 17 - What is the equilibrium constant for the following...Ch. 17 - Calculate the equilibrium constant for the...Ch. 17 - Suppose you eat 28 grams of rhubarb leaves with an...Ch. 17 - The solubility product constant for calcium...Ch. 17 - In principle, the ions Ba2+ and Ca2+ can be...Ch. 17 - A solution contains 0.10 M iodide ion, I, and 0.10...Ch. 17 - A solution contains Ca2+ and Pb2+ ions, both at a...Ch. 17 - Buffer capacity is defined as the number of moles...Ch. 17 - The Ca2+ ion in hard water can be precipitated as...Ch. 17 - Some photographic film is coated with crystals of...Ch. 17 - Each pair of ions below is found together in...Ch. 17 - Each pair of ions below is found together in...Ch. 17 - The cations Ba2+ and Sr2+ can be precipitated as...Ch. 17 - You will often work with salts of Fe3+, Pb2+, and...Ch. 17 - Aniline hydrochloride, (C6H5NH3)Cl, is a weak...Ch. 17 - The weak base ethanolamine. HOCH2CH2NH2, can be...Ch. 17 - For the titration of 50.0 mL of 0.150 M...Ch. 17 - A buffer solution with it pH of 12.00 consists of...Ch. 17 - To have a buffer with a pH of 2.50, what volume of...Ch. 17 - What mass of Na3PO4 must be added to 80.0 mL of...Ch. 17 - You have a solution that contains AgNO3, Pb(NO3)2,...Ch. 17 - Once you have separated the three salts in Study...Ch. 17 - Suggest a method for separating a precipitate...Ch. 17 - Which of the following barium salts should...Ch. 17 - Explain why the solubility of Ag3PO4 can be...Ch. 17 - Two acids, each approximately 0.01 M in...Ch. 17 - Composition diagrams, commonly known as alpha...Ch. 17 - The composition diagram, or alpha plot, for the...Ch. 17 - The chemical name for aspirin is acetylsalicylic...Ch. 17 - Aluminum hydroxide reacts with phosphoric acid to...

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