The azide ion ( N3-) is a weakly bound molecular ion. Formulate its MO structure for localized s bonds and delocalized p bonds. Do you expect N3 and N3+o be bound as well? Which of the three species do you expect to beparamagnetic?

Q: ase on molecular orbital diagrams and the bond order, rank CO, NO, and O2 molecules in order of…

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Q: Use ligand group orbital approach to describe the bonding in [CO3] 2- . Include schematic…

A: Carbonates [CO3] 2-are polyatomic ligands. They are found to bind to two or three metals…

Q: 3. For each of the following molecules or ions: i. Write an MO energy level (orbital correlation)…

A: Bond order = (Number of electrons in BO/Number of electrons in ABO)/2

Q: (a) Sketch the molecular orbitals of the H2- ion and draw itsenergy-level diagram. (b) Write the…

A: “Since you have posted a question with multiple sub-parts, we will solve the first three subparts…

Q: How can a molecular orbital diagram predict the energy of the d-orbital splitting (using the σ…

A: The MOT of the octahedral complex in the presence of different donor ligands are given below:

Q: Q3. Draw the d-orbital splitting diagrams of the central metal ions in a. Heptacyanoosmate(IV) b.…

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Q: Draw and label the molecular orbital (MO) diagrams for C2 and C2 2– . Give the MO ground state…

A: C has 6 valence electrons therefore, C2 will have 6×2=12 electrons.

Q: 1-The bond order of a diatomic molecule is defined A. as one half the difference between the number…

A: As per the rules, only the first three sub-parts of a question can be answered: Co-ordination…

Q: does NO shows paramagnetic behaviour?

A: When a species has unpaired electrons in its outermost orbital it is said to paramagnetic whereas…

Q: (a) What are the relationships among bond order, bondlength, and bond energy? (b) According to…

A: (a)Bond order determines the number of bonds present between the two atoms. Bond order 1 represents…

Q: Use the MO theory to explain the fact 02 IS paramagnetic and has a double bond A diacram of the

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Q: The photoelectron spectrum of CO has four major peaks with ionization energies of 14.5, 17.2, 20.1,…

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Q: =c= N: H - C= N: N: CN32- FCN HCN OCN

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Q: (1) Show the all shapes of bonding and antibonding molecular orbitals (MOs) by combinations of two p…

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Q: State  the net number of  bonding electrons  between  xenon  and the   four fluorines in [XeF4]…

A: In this, w eneed to determine the number of bonding electrons in the XeF4 as per the given molecular…

Q: Xenon tetrafluoride reacts with antimony pentafluoride toform the following ionic complex:…

A: (a) Given that Xenon tetrafluoride reacts with antimony pentaflouride. The shape of Xenon…

Q: The major component of household bleach is sodium hypochlorite. In South Africa, bleaching solution…

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Q: Draw and explain all the properties of CO and NO with the help of molecular orbital diagram

A: Molecular orbitals are formed by the linear combination of atomic orbitals that must have comparable…

Q: Use MO diagrams and the bond orders you obtain fromthem to answer: (a) Is O₂⁻ stable? (b) Is…

A: The molecular orbital theory is used to explain the bonding in molecules that cannot be explained by…

Q: Q3 a) Calculate the CFSE for the following ions in an octahedral field: Cr2*, Co2*, Mn²+ and Zn²+ ?…

A: CFSE = Crystal Field Stabilization Energy All given metals belongs to 3-d period d orbitals energy…

Q: Use the MO theory to explain the fact that 0, is paramagnetic, and has a double bond. A diagram of…

A: According to Molecular Orbital Theory, molecular orbitals are formed by a linear combination of…

Q: Which of the following statements is true regarding the T molecular orbitals of benzene? All six…

A: In the first question, we will see which statement is true about molecular orbital for Benzene. You…

Q: 1. Does the molecule Ne, exist? A. Draw a molecular orbital energy diagram for Ne2. B. Write the…

A: 1. No, Ne2 molecule does not exist. A. Molecular orbkital diagram for Ne2 is

Q: 3. Sketch the molecular orbital diagrams for O2, O2 (superoxide, 1e reduction of O2) and 02…

A: Bond order for O2,           It has two unpaired electron so it is paramagnetic.

Q: Explain the followings for the anions present magnesiumfloride and sodiumperoxide. i) Molecular…

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Q: Using an MO energy-level diagram, deterine whether you would expect the O2 molecule to have a lower…

A: Ionisation energy is the amount of energy needed to remove an electron from the atom or the…

Q: 1. Sketch the MO diagram of the following species and fill the molecular orbitals with electrons.…

A: MO diagram of : Li2 , Ne2 , N2+, B2+

Q: Explain Molecular Orbital Theory of CO with suitable diagram

A: The electronic configuration of carbon (atomic number 6) is 1s2 2s2 2p2 The electronic configuration…

Q: Choose the nido borane cluster from the following A) BH12 2- B) B„H" C) C̟B1,H10 D) C,B,H,

A: There are various types of borane structure-  1- closo borane 2- nido borane 3- arachno borane 4-…

Q: 6. Using a molecular orbital (MO) energy diagram, indicate the magnetic properties of the following:

A: MOED= molecular orbital energy diagram We can determine 1)bond order, 2)bond length3)magnetic…

Q: To answer the next several questions, sketch the MO diagrams for the following molecules: 02. 022+,…

A: According to the molecular orbital theory, the atomic orbitals combine to forms molecular orbitals.…

Q: Formulate the MO structure of (NO;) for localized o bonds and de-localized 7 bonds. Is it linear or…

A: The NO2+ molecular ion has 16 valence electrons (five from nitrogen atom, six from oxygen atom). For…

Q: Draw clearly labelled molecular orbital diagrams for C2* and NO. Indicate the bond order and number…

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Q: Discuss the nature of the bonding in the nitrite ion (NO2). Draw the possible Lewis resonance…

A: The resonance structures of nitrite ion, the steric number, and the geometry of the ion should be…

Q: Platinum hexafluoride is an extremely strong oxidizing agent. It can even oxidize oxygen, its…

A: The answers are given below

Q: Draw a molecular orbital diagram for NF and calculate the bond order. Also, comment on its magnetic…

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Q: Consider these following ions: O2-, N22-, Li2+ and O22-   a. Based on molecular orbital theory…

A: Molecular orbital theory is used to represent the arrangement of electrons in the orbital. From…

Q: The link order by TOM is three.   VI. The type of bond by Lewis theory is triple.   VII. The…

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Q: Structure of the Bis-( dimethylglyoximato) nickel(II) (write the C.N , geometry type):

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Q: Bond Order Magnetic Property Bond Distance (a, b, c, d) (longest=a, shortest=d) Species O,+…

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Q: The photoelectron spectrum of CO has four major peakswith ionization energies of 14.5, 17.2, 20.1,…

A: The peaks of molecular orbitals of CO should be assigned and a quantitative energy level correlation…

Q: Use group theory and the character table given to determine a qualitative molecular orbital energy…

A: H3O+ has the pyramidal shape as shown below: Its point group is C3v.

Q: Write out the orbital box diagram for Mo2+, and state whether it’s diamagnetic of paramagnetic.  You…

A: Atomic Number of molybdenum (Mo) is 42. So, the electron configuration of Mo will be : [Kr] 4d5 5s1

Q: What kinds of intermolecular interactions would occur in NH3 (1)? What kinds of intermolecular…

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Q: Draw the hybridization for the metal centre of the complex below

A: According to Valence bond theory: Electrons in a molecule occupy atomic orbitals rather than…

Q: The atomic orbital, AO, contributions of penta-1,3-denyl cation are drawn in random order below.…

A: The molecule considered is penta-1,3-dienyl cation.

Q: . The term F (for free ion) is split in an octahedral field to: O A1+ E+ T2 O A2 + T1 + T2 O A1 + E+…

A: The given term F is from Russell Saunders coupling. In Russell Saunders coupling is there three…

Quantum Mechanical Treatment of the Valence Bond Theory

Quantum mechanical treatment of valence bond theory refers to the relationship established between the quantum mechanical theory and the valence bond theory to describe the chemical bonding in a particular molecule.