The major component of household bleach is sodium hypochlorite. In South Africa, bleaching solution is known commonly as "JIK". The solution is made by dissolving the ionic solid in water. Construct a Molecular Orbital diagram using the anion of the solid mentioned above. Label all AO's, MO's and any other relevant features on the diagram. Calculate the bond order for the anion and comment on any possible physical properties that may be evident from your calculation and the MO diagram. Use the Table given below to help you construct your MO diagram. TABLE 5.2 Orbital Potential Energies Orbital Potential Energy (eV) Atomic Number 1s Element 25 2p 35 3p 4p H -13.61 2 Не -24.59 3 Li -5.39 4 Be -9.32 5 B -14.05 -8.30 -19.43 -10.66 7 -25.56 -13.18 8 -32.38 -15.85 F -40.17 -18.65 10 Ne -48.47 -21.59 11 Na -5.14 12 Mg -7.65 13 Al -11.32 -5.98 14 Si -15.89 -7.78 15 P -18.84 -9.65 16 -22.71 -11.62 17 CI -25.23 -13.67 18 Ar -29.24 -15.82 19 K -4.34 20 Ca -6.11 30 Zn -9.39 31 Ga -12.61 -5.93 32 Ge -16.05 -7.54 33 As -18.94 -9.17 34 Se -21.37 - 10.82 35 Br -24.37 -12.49 36 Kr -27.51 -14.22

The major component of household bleach is sodium hypochlorite. In South Africa, bleaching solution is known commonly as "JIK". The solution is made by dissolving the ionic solid in water. Construct a Molecular Orbital diagram using the anion of the solid mentioned above. Label all AO's, MO's and any other relevant features on the diagram. Calculate the bond order for the anion and comment on any possible physical properties that may be evident from your calculation and the MO diagram. Use the Table given below to help you construct your MO diagram. TABLE 5.2 Orbital Potential Energies Orbital Potential Energy (eV) Atomic Number 1s Element 25 2p 35 3p 4p H -13.61 2 Не -24.59 3 Li -5.39 4 Be -9.32 5 B -14.05 -8.30 -19.43 -10.66 7 -25.56 -13.18 8 -32.38 -15.85 F -40.17 -18.65 10 Ne -48.47 -21.59 11 Na -5.14 12 Mg -7.65 13 Al -11.32 -5.98 14 Si -15.89 -7.78 15 P -18.84 -9.65 16 -22.71 -11.62 17 CI -25.23 -13.67 18 Ar -29.24 -15.82 19 K -4.34 20 Ca -6.11 30 Zn -9.39 31 Ga -12.61 -5.93 32 Ge -16.05 -7.54 33 As -18.94 -9.17 34 Se -21.37 - 10.82 35 Br -24.37 -12.49 36 Kr -27.51 -14.22

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter5: Alkenes: Bonding, Nomenclature, And Properties

Section: Chapter Questions

Problem 5.11P: The structure of 1,2-propadiene (allene) is shown to the right. (a) Predict all approximate bond...

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