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Acidic Environment

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Acidic Environment

Oxides of non-metals which act as acids

Non-metals burn in air or oxygen to produce acidic oxides. The addition of water to soluble oxides produces acidic solutions.

Oxides of non-metals which act as acids include:

* Carbon reacts with oxygen when burnt to form carbon dioxide which is acidic in nature. When dissolved in water, it becomes H2CO3 (carbonic acid).

CO2 (g) + H2O (l) →H2CO3 (aq)

* Sulfur burns in oxygen to give sulfur dioxide or sulfur trioxide which is acidic in nature. When dissolved in water, it forms sulfurous acid H2SO3 and sulfuric acid H2SO4 respectively.

[IMAGE]

SO3 (g) + H2O (l) →H2CO4 (aq)

Sulfur …show more content…

Electropositive behaviour increases from right to left across the periodic table and increases down the column. As the electropositivity of the atom increases, so too the basicity of the oxide. The more electronegative the atom, the more acidic the oxide.

Sulfur dioxide & oxides of Nitrogen

The oxides of nitrogen form naturally when lightning strikes cause nitrogen and oxygen in the air to combine. Thus the nitrogen oxides become oxidised to nitric acid, nitrates and nitrites.

N2 + O2[IMAGE] 2NO

Nitrogen monoxide or nitrogen oxide can also be formed (industrially) in internal combustion engines or high temperature combustion reactions in furnaces:

N2 + O2[IMAGE] 2NO

This nitrogen monoxide gas can further react with oxygen in the air to form brown acidic nitrogen dioxide.

2NO + O2[IMAGE] 2NO2

Nitrogen oxides are soluble in water and have known contributions to pollutants (PAN) in photochemical smog as well as its detrimental effects to animal respiratory systems. There are a number of these such oxides including: nitrogen dioxide (NO2), nitrous oxide (N2O) and nitrogen monoxide (NO).

Sulfur dioxide and the oxides of nitrogen profoundly contribute to the acidity of the atmosphere and ultimately, the production of acid rain.

Sulfur dioxide (SO2) is an acidic

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