ANSWERS TO QUESTIONS:
1. What are the significant regions in the titration curve? Relate the characteristics of each region to the pH results obtained.
- There are four significant regions in each titration curve, namely the initial, pre-equivalence, equivalence, and post-equivalence points. These points are named according to its position relative to the equivalence point.
The equivalence point signifies the volume of titrant at which the solution becomes neutral. This is represented in the graph as the drastic change in pH, first with a sudden increase and a sudden decrease of pH.
At the initial point, no titrant has been added yet and the solution’s pH equates to the number of H+ ions originally present in the analyte.
At the
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Using this method, the amount of titrant used for weak acids would be the same as that used for strong acids since it is the number of protons or H+ ions, measured through the pH, which determines the equivalence point. With normal titrations of strong acids and bases, since H+ completely dissociates, similar concentrations with a weak acid and strong base titration would not be the same since weak acids do not dissociate completely. Another advantage of potentiometric titration is the fact that indicators are not used, therefore human error due to failure of recognition of color change may be avoided.
5. Discuss possible reasons behind the discrepancies (if any) in the experimental and theoretical pKa values.
- Human errors may have affected the results, such as miscalculations, overtitrations and failure of determination of the right pH value since the pH meter tends to fluctuate. Another source of error could be from the pH meter apparatus itself, particularly the electrodes since the classroom’s conditions are not perfect. The failure to rinse the electrodes may result to drastic changes as well. Another error may result from the failure in accuracy of the analytical balance since it has been used for several years prior.
6. What are the possible sources of errors and their effect on the calculated parameters? Rationalize.
- One of the members of the group accidentally touched the magnetic stirrer therefore contaminating the whole set-up. Since it cannot be
pH was recorded every time 1.00 mL of NaOH was added to beaker. When the amount of NaOH added to the beaker was about 5.00 mL away from the expected end point, NaOH was added very slowly. Approximately 0.20 mL of NaOH was added until the pH made a jump. The pH was recorded until it reached ~12. This was repeated two more times. The pKa of each trial are determined using the graphs made on excel.
We know that that the end point of the titration is reached when, after drop after careful drop of NaOH, the solution in the flask retains its pale pink color while swirling for about 30
9) Filter the ppt formed as result of step 7 from the newly acidic solution.
Figure 1: Amount of O2 gas curves to the time at which it was measured according to low, medium, and high pH.
A buffer is a solution that resists changes in pH when H+, OH-, or H20 is added. By using standard lab equipment, a lab pro diagnostic tool, and acidic and basic solutions, the pH can be found. By recording the pH while adding a base or an acid gradually to a buffer solution you can find the capacity of each buffer to resist drastic changes in pH. The best buffers will keep a solution from becoming either too acidic or basic with the addition of a strong base or acid.
Question: The equivalence points of the two titration curves were not in the same pH range. Explain. (Why was the pH at the equivalence point different for the two different acids?)
During a titration the pH of the solution will be monitored using a pH meter from that we get a titration curve. The titration curve is then used to determine the equivalent molecular weight and Ka value of the unknown weak acid, from that we are
ii. The second part of the titration series involves titration of NaOH with Hydrochloric acid (HCL). Again, three reps of titration and a blank titration have to be completed. A volumetric pipet is used to measure 10.00mL of HCL into three labeled conical flasks. Then the flasks are filled with deionized water until about the 50mL mark. A buret is
To improve the results from the experiment buffer solutions that were not whole pHs could have been used e.g. pH 4.5, 5.5 etc. This would have provided more reliable results as a wider range of results would have been produced. Using pHs with decimals would also help to more accurately determine the optimum pH as the optimum may have been above or below the pH stated in the hypothesis; 8. In this experiment however the optimum is taken at 8 because the graph does not rise again.
By using acid-base titration, we determined the suitability of phenolphthalein and methyl red as acid base indicators. We found that the equivalence point of the titration of hydrochloric acid with sodium hydroxide was not within the ph range of phenolphthalein's color range. The titration of acetic acid with sodium hydroxide resulted in an equivalence point out of the range of methyl red. And the titration of ammonia with hydrochloric acid had an equivalence point that was also out of the range of phenolphthalein.. The methyl red indicator and the phenolphthalein indicator were unsuitable because their pH ranges for their color changes did not cover the equivalence points of the trials in which they were used. However, the
For this experiment, titrations on a weak acid, acetic acid, and a buffer were performed. Acetic acid was titrated with NaOH in order to observe the half-equivalence point as well as the equivalence point. Then, the buffer and the buffered acetic acid solution prepared faced additional titration with NaOH and HCl to evaluate the differing buffering effects following the addition of a strong acid and strong base. Finally, the buffer’s buffering capacity was calculated. If the experiment were to be repeated, it would be interesting to observe the buffering effects following a titration between a weak base and a buffer instead with greater concentrations. The change in the concentration following the preparation of buffer with a weak base and its conjugate acid would pose for an interesting experiment to observe an increase in the buffering capacity.
1. To titrate a hydrochloric acid solution of “unknown” concentration with standardized 0.5M sodium hydroxide.
2. Following solutions are added to the tubes and the pH of each tube is determined:
The first source of error that caused different results between group was that the groups misread the colour of the indicator at exactly the equivalence point. The other group could have misjudged light pink for clear and could’ve kept pouring the titrant till the color of the indicator changed dark pink ,which will result in a higher number of moles of the solution in your buret than in your flask. The extra moles of titrant used would give incorrect measurement since the amount KOH used would to titrate HCl would increase and giving a higher concentration for HCl. To avoid this source of error groups should used pH meter instead of phenolphthalein.A pH meter giver reading from 1-14 and doesn’t require judgment. The group would know solution is basic when the reading is 7 and they would stop pouring the titrant. This would avoid extra titrant in the solution and give a more accurate concentration.
When using different methods to measure pH levels there are some tools that can be useful. Some more than others but by putting into action the different methods it may determine which tools will work best and give the best results when testing the pH within a solution. The pH, which stands for the proportion of hydrogen ions in a solution, could be acidic (acidosis), neutral or basic (alkaline). The pH scale goes from numbers 1 through 14. A pH of 7 is neutral;