Vick Hung
Draft 1
How does carbon compound in a alcohol affect the energy release from the combustion of the alcohol
Introduction
In Organic Chemistry unit of our Chemistry class, our teacher taught us about the different types of alcohols, and the different characteristics of them. On my own time with personal interest, I learned more about alcohol, and noticed potential in these substance. The presence of alcohol could be found in many places, from food and ingredient in the kitchen, to bio fuel in technologies.
A most commonly used alcohol is ethanol. ethanol has been in our lives for a long time. It is used in cleaning, and is also introduced to industrial usage. Ethanol is also blend into gasoline to reduce air pollution in combustion
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2070
358
1494
463 - 2778
3216
total enthalpy of reaction 4731
- 5994
-1263
propan-1-ol C-C C-H C-O O=O H-O product of reaction H-O C=O bond enthalpy 346 414 358 498 463 463 804
# of bonds 2 7 1 4.5 1 8 6 total bond enthalpy 692
2898
358
2241
463 - 3704
4824
total enthalpy of reaction 6652
- 8528
-1876
butan-1-ol C-C C-H C-O O=O H-O product of reaction H-O C=O bond enthalpy 346 414 358 498 463 463 804
# of bonds 3 9 1 6 1 10 8 total bond enthalpy 1038
3726
358
2988
463 - 4630
6432
total enthalpy of reaction 8573
- 11062
-2489
pentan-1-ol C-C C-H C-O O=O H-O product of reaction H-O C=O bond enthalpy 346 414 358 498 463 463 804
# of bonds 4 11 1 7.5 1 12 10 total bond enthalpy 1384
4554
358
3735
463 - 5556
8040
total enthalpy of reaction 10494
- 13596
-3102
Hexan-1-ol C-C C-H C-O O=O H-O product of reaction H-O C=O bond enthalpy 346 414 358 498 463 463 804
# of bonds 5 13 1 9 1 14 12 total bond enthalpy 1730
5382
358
4482
463 - 6482
9648
total enthalpy of reaction 12415
- 16130
-4285
Compare data from bond enthalpy calculation to Data from PT Data
meth eth prop but pen hex
Bond enthalpy calculation -650 -1263 -1876 -2489 -3102
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although both the lines showed a gradual increase, all the calculated values are lower then those of the Physical and Thermochemical Data except for hexan-1-ol. but
Conclusion overall, the investigation showed a positive correlation between the increase of carbon number in the linear alcohol homologous series, and the increase in enthalpy of combustion, which supports my hypothesis. Thus with the investigation of this experiment, it is to be concluded that, ignoring the cost of production, the more carbon in a alcohol, the more energy is released from the combustion of the molecule with oxygen.
Bibliography
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Many combustion reactions involve the burning of organic compounds called hydrocarbons, compounds containing the elements carbon and hydrogen, or other organic compounds. When a hydrocarbon is burned completely, the products of the combustion reaction are usually carbon dioxide and water. Natural gas, propane, and wood all burn to produce carbon dioxide and water as the products.
From the data analysed, a clear trend is seen. As the amount of carbon chains (and consequently molar mass) increases, so does the heat of combustion released. The hypothesis was stated as: “because 1-hexanol has more carbon bonds, it will produce the most amount of heat in the shortest period of time. By following the same reasoning, it is suggested that 1-hexanol will be followed by 1-pentanol and 1-butanol, respectively.” The experimental values show there is a linear relationship between the carbon chains and molecular weight, and the heat of combustion
For instance, pentan-1-ol, the alcohol utilised to synthesis 1-pentyl ethanoate, is relatively flammable due to the hydroxyl functional group attached to the molecule. Therefore, in order to prevent severe burns, a laboratory coat and safety glasses were worn. The experiment was additionally performed whilst standing up, so that if the aliquot of pentan-1-ol ignited,
Different alcohols (methanol, ethanol, and 1-propanol) will all be used within their respective spirit burners.
Calculate the value of the standard free-energy change, ∆G˚, for the combustion of phenol at 25° C.
An Investigation into the Enthalpies of the Combustion of Alcohols = == == == ==
Generally ethanol is an alcohol found in alcoholic drinks. At 100% concentration, it is pure and a colourless liquid with a strong odour (due to weak Van der Wall forces :D. Ethanol is produced by the fermentation of carbohydrates in yeast cells and is used frequently as a solvent.
According to Oxford Dictionaries, alcohol is a colorless volatile flammable liquid that is produced by the natural fermentation of sugars and is the intoxicating constituent of wine, beer, spirits, and other drinks, and is also used as an industrial solvent and as fuel (Fowler, H. W., Fowler, F. G., & Murray, J. A. (1964). The concise Oxford dictionary f
According to the graph in figure 5, as the number of Carbon atoms in alcohol increased by 1, the change in standard enthalpy of combustion would increase by around 200 kJ/mol. This is proven as the equation of the linear line (protruding from the bottom left to the top right of the graph) is y=199.81x, where x is the number of Carbon atoms, y is the standard enthalpy of combustion and 199.81 is the gradient of the line and how much the standard enthalpy of combustion would increase by when multiplied by x. There were also errors/uncertainties that were shown in the graph and result tables. The average error of each of the different alcohols was of 6.51%. Thus, as the change in standard enthalpy of combustion of the alcohols increased, the uncertainties and errors became greater. The size of the uncertainties can be seen becoming greater as the size of the change in standard enthalpy of combustion increases in the graph of figure 5 and the results table of figure
Many people assume alcohol is nothing more than liquor or rubbing alcohol; however, this is not the case. There are many different types of alcohol including some of the alternate fuels we put into our vehicles. Over the course of my working life I have come into contact with many different alcohols, but Isopropyl Alcohol, or 2-propanol, was one of the ones that I encountered the most and I have always wondered exactly what it is. 2-propanol is a very interesting molecule and has a lot of uses for products in many different markets. Because of this, many people come into contact with it and do not even know it. There are many important advances going on with the development of isopropanol that could potentially change our lives. Although, it is important to know and understand the products that you are coming into contact with because some of them might be
This graph on the other hand, shows a pattern between the scales of carbon lengths in molecules. The higher amount of carbon in a longer chain, results in a higher molar heat of combustion. This supports the theory behind bond energy as more bonds break, more bonds form which add up to making a higher molar heat of combustion.
In Whiting S. Albert’s article “Alcohol Use Is Harmful” he stated that alcohol is a chemical that contains hydrogen and carbon. Whiting stated further that the active ingredient of alcohol is ethyl alcohol, which is also known as ethanol. Alcohol is one of the few things that human being consume that do not need digestion. Alcohol appears the bloodstream immediately, thus, its intoxicating effects are felt instantly (1). “High levels of mortality, morbidity, and social malaise are associated with abuse of alcohol, and increasing numbers of women and youth are abusing alcohol” (Ferreira and Darryn 1). “Alcohol slows down the function of all living cells, especially those in the brain” (Whiting 1), which causes thinking to be impaired. Alcohol is probably the most used drug worldwide. “Three in ten adults 18 years of age and over have had alcoholism and/or engaged in alcohol abuse at some point in their lives …” (“Impact of Alcoholism” 1). According to Centers for Disease Control and Prevention,
The chemical formula of ethanol is made up of 2 carbons, 6 hydrogens and 1 oxygen and is classed as an alcohol (Material safety data sheet, 2001). Ethanol has a boiling point of 78.5c, density of .789 and a molecular weight of 46.0684mol (Biofuels Association of Australia, 2015). Ethanol is now usually used as a fuel for vehicles in its pure form as a replacement for gasoline, where it is blended with gasoline to improve vehicle emissions and power (Biofuels Association of Australia, 2015).
As we all know, alcohol is a product that has provided a variety of functions for people in the world. Alcoholic beverages have been consumed by humans in the very early time, they were one of the most popular drink and have been widely used in everywhere of the world. Also they were used medicinally, chemically, physically and so on.
The production and consumption of alcohol occurs in most cultures of the world, from hunter-gatherer peoples to nation-states.[2][3] Alcoholic beverages