Estimation of the Activation Energy for the Iodination of Acetone Through the Effect of Temperature on the Rate Constant
Joel Costa, Alex Fuentes, Michael Chea, Rex Nwerem
Dr. Morgan Ferguson
July 9, 2013
ABSTRACT |
It is often important to determine the rate at which a chemical reaction takes place, i.e., how fast it yields the desired products. Temperature is one of the factors that influence the rate of reactions and it does so by providing energy to reactant particles so that a larger fraction of them reach the activation energy necessary to start the reaction. The purpose of this experiment was to estimate the Activation Energy for the Iodination of Acetone through the analysis of the relationship between the rate constant
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Mathematically, given that the temperature is the denominator of a negative exponent, the larger the temperature, the larger the rate constant and, consequently, the faster the reaction (increased rate). From this relationship, it is also implied that reactions with lower activation energies, keeping the temperature constant, will also have larger rate constants and, therefore, happen at a faster rate.
Taking the natural logarithm of both sides of the Arrhenius equation, a linear relationship is obtained between the natural logarithm of the rate constant k and the reciprocal of the temperature:
Knowing the rate law of a reaction, conducting several trials of that reaction with a known and fixed concentration of reactants, it is possible to determine the rate constant for different temperatures and use the data obtained to graph this linear relationship. Determining the slope of the linear equation and dividing it by the universal gas constant will give the value of the activation energy for the reaction.
For the Iodination of Acetone,
given that the rate does not depend on the concentration of Iodine, the rate can be measured by the change of the concentration of this reactant, which is determined by the known initial concentration and the zero
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Temperature is a measure of kinetic energy. As this movement increases, collision rate and intensity, and therefore reaction rates, increase. This experiment was conducted to determine if there is a minimum temperature that increase kinetic energy and denature enzymes to slow enzymatic reactions or fail to catalyze them. The experimental results indicate an increase in temperature will increase reaction rates until proteins denature.
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Abstract: This two part experiment is designed to determine the rate law of the following reaction, 2I-(aq) + H2O2(aq) + 2H+I2(aq) + 2H2O(L), and to then determine if a change in temperature has an effect on that rate of this reaction. It was found that the reaction rate=k[I-]^1[H2O2+]^1, and the experimental activation energy is 60.62 KJ/mol.
Is this a linear relationship? What happens to the initial reaction rate as substrate concentration increases?
The hypothesis tested in this experiment was, if the temperature of enzyme catalysis were increased, then the reaction rate would increase, because enzyme-catalysis reacts by randomly colliding with substrate molecules, and the increase in temperature increases the speed of collision or reaction rate. The final data collected for the experiment was positive with my hypothesis. The coffee filter, covered in potato solution, sank and rose at a faster pace in the hydrogen peroxide when the temperatures were raised.
9. Does temperature have any effect on reaction rate? If so, why does it occur?
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To vary the concentrations of each reactant along with the sulphuric acid in order to observe and measure its effect on the overall rate of reaction in absorbance using colourimetry.
Introduction: The theory behind this experiment is the heat of a reaction (∆E) plus the work (W) done by a reaction is equal to
Kinetics of chemical reactions is how fast a reaction occurs and determining how the presence of reactants affects reaction rates. In this experiment the rate of reaction for Fe+3 and I- is determined. Because the rate of chemical reactions relates directly to concentration of reactants, the rate law is used to find the rate constant, and calculated with specified temperatures.
Martin Novick Group 14, Chemical Engineering Laboratory Submitted to Prof. David B. Henthorn September 25, 2012 Summary The goal of this project was to determine the pre-exponential factor, k o , the activation energy, E, and the reaction rate constants, k, of the saponification process of ethyl acetate using sodium hydroxide (NaOH) at 5 temperature between 15 and 25 degrees Celsius. Two trails were performed at temperatures 16, 18, 20, 22, and 24 degrees Celsius. The main equipment of the project were the jacketed beaker batch reactor and the LabPro conductivity probe. The solution’s conductivity throughout the reaction was collected and plotted in a linearized plot against time to
The key aim of this experiment was to determine the rate equation for the acid-catalysed iodination of acetone and to hence consider the insinuations of the mechanism of the rate equation obtained.