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Iodination of Acetone

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Estimation of the Activation Energy for the Iodination of Acetone Through the Effect of Temperature on the Rate Constant

Joel Costa, Alex Fuentes, Michael Chea, Rex Nwerem

Dr. Morgan Ferguson
July 9, 2013

ABSTRACT |

It is often important to determine the rate at which a chemical reaction takes place, i.e., how fast it yields the desired products. Temperature is one of the factors that influence the rate of reactions and it does so by providing energy to reactant particles so that a larger fraction of them reach the activation energy necessary to start the reaction. The purpose of this experiment was to estimate the Activation Energy for the Iodination of Acetone through the analysis of the relationship between the rate constant …show more content…

Mathematically, given that the temperature is the denominator of a negative exponent, the larger the temperature, the larger the rate constant and, consequently, the faster the reaction (increased rate). From this relationship, it is also implied that reactions with lower activation energies, keeping the temperature constant, will also have larger rate constants and, therefore, happen at a faster rate.
Taking the natural logarithm of both sides of the Arrhenius equation, a linear relationship is obtained between the natural logarithm of the rate constant k and the reciprocal of the temperature:

Knowing the rate law of a reaction, conducting several trials of that reaction with a known and fixed concentration of reactants, it is possible to determine the rate constant for different temperatures and use the data obtained to graph this linear relationship. Determining the slope of the linear equation and dividing it by the universal gas constant will give the value of the activation energy for the reaction.

For the Iodination of Acetone,

given that the rate does not depend on the concentration of Iodine, the rate can be measured by the change of the concentration of this reactant, which is determined by the known initial concentration and the zero

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