Essay on Potentiometeric Titrations

The purpose of this semester long experiment was to determine an unknown organic acid. An organic acid is an organic compound with acidic properties. A base reacts with acids to form salts. Titrations are used to determine the concentration of unknown substances. The purpose of the KHP experiment was to determine the molarity of NaOH. HCl titrations are mainly to check technique and used to verify the molarity of NaOH solution. The hypothesis is that this acid is C4H3OCOOH.

mL cylinder to the beaker on the stir plate and empty it into the beaker. Place the pH probe in the beaker and record the pH in the data table. Drag the beaker to the red disposal bucket. Double-click the bottle of NaHCO3 to move it to the Stockroom counter. Repeat steps 5 and 6 for KNO3.

To start out this study the difference between acids and bases has to be identified. Acids have very low pHs and have a high concentration of hydronium ions, while bases have a high pH and have a high concentration of hydroxide ions. The difference between strong bases and acids, and weak bases and acids is the amount of dissociation. Strong bases and acids dissociate a large amount and let go of their ions in solution, while weak bases and acids may only let go of some of their ions. This is important because if the unknown solutions aren’t strong acids or bases then using their ions to calculate the pH of the solutions will give false results (Diffen 2012).

The purpose of this experiment was to determine the pKa, Ka, and molar mass of an unknown acid (#14). The pKa was found to be 3.88, the Ka was found to be 1.318 x 10 -4, and the molar mass was found to be 171.9 g/mol.

Measure 500ml of tap water in the 500cm3 beaker, then measure 5g of sodium hydrogen carbonate using the 50cm3 beaker and weight scale and place in the beaker of water, using the glass rod to dissolve it into the mixture.

Table 2: Consists of color extract taken from a red cabbage for a natural indicator. The pH reading that was measured by using the pH meter and the result of the pH reading to determine whether the solution was acidic or basic.

The titration worked well and yielded decent results. It was found that 72.10 mg of ascorbic acid is contained within a serving of lemonade.The %w/w of ascorbic acid is .30%. The volumes collected and observations made worked out to give proper and expected values. Rinsing the burette and pipette was important to this as it removed any water or dust inside. This meant that final volumes and calculations were more precise as there were fewer sources of error. The standard deviation obtained from the four trials was 0.22 mL. Much of this error is due to the rapid colour change. This made it difficult to precisely end the titration when the endpoint was reached. Another source of error is found in the assumption that because a colour change happened the proper reaction had occurred. This assumption while very basic and small potentially had a slight impact on final results. Titrations are very simple and therefore are empirical, and based off simple measurements with these simple assumptions accuracy decreases and error

ii. The second part of the titration series involves titration of NaOH with Hydrochloric acid (HCL). Again, three reps of titration and a blank titration have to be completed. A volumetric pipet is used to measure 10.00mL of HCL into three labeled conical flasks. Then the flasks are filled with deionized water until about the 50mL mark. A buret is

During a titration the pH of the solution will be monitored using a pH meter from that we get a titration curve. The titration curve is then used to determine the equivalent molecular weight and Ka value of the unknown weak acid, from that we are

The standardized concentration of NaOH was used to identify the unknown acids, this value is shown is experiment 16.1. This mean standardized concentration was 0.0784 M. By titrating a known amount and concentration of this standardized base to the unknown acid, a titration curve and its derivative could be plotted in order to find the molar mass and acid dissociation constant. The first unknown acid titrated, BGYW, was identified to be Maleic acid, C4H4O4.

By using acid-base titration, we determined the suitability of phenolphthalein and methyl red as acid base indicators. We found that the equivalence point of the titration of hydrochloric acid with sodium hydroxide was not within the ph range of phenolphthalein's color range. The titration of acetic acid with sodium hydroxide resulted in an equivalence point out of the range of methyl red. And the titration of ammonia with hydrochloric acid had an equivalence point that was also out of the range of phenolphthalein.. The methyl red indicator and the phenolphthalein indicator were unsuitable because their pH ranges for their color changes did not cover the equivalence points of the trials in which they were used. However, the

The experiment was carried out to determine if the malic acid or apple acidity is affected by their ripeness. It is hypothesized that the acidity level of the apple fruit would reduce as the fruit ripens. The experiment was performed by squeezing out the juices from the apple fruit and measuring the juice of the apple with a pH probe. The outcome of the experiment was that the unripe fruits had a high acidic level. The content of malic acid decreases from the unripe fruits until the maturity and the fruit pH fluctuates as it ripens. The pH of the unripe apple was 3.2, with the ripe apple, the pH was 3.9 and with the apples that had time to ripen in the laboratory the pH level was 4.5.

First, three titration curves and three second derivative curves were created to determine the average pH at the half-equivalence point from the acetic acid titrations. Titration curves were used as visuals to portray buffer capacity. The graphs and a table, Table 1, that showcased the values collected were created and included below. The flat region, the middle part, of Figures 1, 2 and 3, showed the zone at which the addition of a base or acid did not cause changes in pH. Once surpassed, the pH increased rapidly when a small amount of base, NaOH, was added to the buffer solution. Using the figures below and

The titration of a strong base (NaOH) against a weak acid (Histidine monohydrochoride ) enables us to know of properties of the weak acid (histidine). Such properties include the pKa of the acid and the pH range of the buffering capacity. One way to relate pH to pka would be through the Henderson – Hasselbalch equation as stated below.

In this lab a acid-base indicator phenolphthalein was used to determine endpoint of a reaction HCl(aq) and KOH(aq). At the end point all of the HCl(aq) would have reacted with KOH(aq), and the pH becomes 7. The phenolphthalein would changed colours from colourless to pink indication when enough KOH(aq) was added. The purpose of numerous trials was to use the average volume of the 3 trials with similar measurements.