Chapter 15 (not much on E) Thermodynamics: Enthalpy, Entropy & Gibbs Free Energy Thermo 2 Thermodynamics: thermo = heat (energy) dynamics = movement, motion Some thermodynamic terms chemists use: System: the portion of the universe that we are considering open system: energy & matter can transfer closed system: energy transfers only isolated system: no transfers Surroundings: everything else besides the system Isothermal: a system that is kept at a constant temperature by adding or subtracting heat from the surroundings. Heat Capacity: the amount of heat energy required to raise the temperature of a certain amount of material by 1°C (or 1 K). Specific Heat Capacity: 1 g by 1°C Molar Heat Capacity: 1 …show more content…
Thermo 9 Standard Enthalpy of Formation -- H f The amount of heat absorbed (endothermic) or released (exothermic) in a reaction in which one mole of a substance is formed from its elements in their standard states, usually at 298 K (25°C). Also called heat of formation. H = 0 for any element in its standard state (the f natural elemental form at 1 atm or 1 M) at 298 K. EXAMPLES: C(graphite, s) + O 2 (g) H° = 0 kJ/mol rxn CO2 (g) 0 kJ/mol elements in their standard states negative sign heat released -- exothermic rxn 393.5 kJ/mol product (one mole) H° (CO2 ) = f 393.5 kJ/mol Thermo 10 2H2 (g) + O 2 (g) H° = 0 kJ/mol rxn 0 kJ/mol 2H2 O (g) 483.6 kJ/ 2 mol elements in their standard states product (two moles) divide by 2 to put on per mole basis!! negative sign heat released -- exothermic rxn H° (H2 O) = f 241.8 kJ/mol Note that I usually will not have you calculate Hfº on homeworks or tests – so you generally don’t have to worry about normalizing your answer to a per mole basis. Hess 's Law -- Adding Reactions The overall heat of reaction (Hrxn) is equal to the sum of the Hf (products) minus the sum of the Hf (reactants): H° = rxn (# eqiv) H° (products) (# eqiv) H° (reactants) f f Therefore, by knowing Hf of the reactants and products, we can determine the Hrxn for any reaction that involves
The molar heat of combustion of a substance is the quantity of heat liberated when one mole of that substance is burnt completely in air. In the case of a hydrocarbon, the products are carbon dioxide and water.
The specific heat of a substance is defined as the amount of heat that must be absorbed or lost or 1 g of that substance to change its temperature by 1°C.
Every chemical reaction that exists is one of two things, endothermic or exothermic. The Greek root therm means temperature or heat, which tells us that there is energy exchange! Endo means within while exo means outside, so these types of reactions are the opposite. Endothermic reactions are those which absorb heat during the reaction. They take in more energy than they give off, which leaves the surroundings cooler than the starting point. Evaporation of water by sunlight is a great example. The sun and the liquid water combine and the water absorbs energy and eventually becomes as gas. Exothermic reactions are exactly the opposite. While they take some energy to get going, called the activation energy of reaction, these reactions give off heat during
Enthalpy is the total energy content of the reacting materials. Enthalpy is given the symbol H. the only was to measure enthalpy is the measure the change in
Every science has an idiosyncratic vocabulary associated with it, and thermodynamics is no exception. In everyday life, everything uses energy, but does that mean the energy is lost? Of that energy that is being used, what is the quality of that energy and is it increasing or decreasing? Through thermodynamics, these types of question can be solved using the different laws. Thermodynamics can be defined as the science of energy. The name thermodynamics is derived from the Greek words therme, meaning heat and dynamis, meaning power. Thermodynamics is at work in our everyday lives, yet most people have no idea it 's there.
When you measure the energy with a thermometer, that is actually the average energy of all molecules in the system. The molecules vary: some with loads of energy, some with little energy; this allows molecules to move around because there is space for all. When the atoms bump into each other, energy is transferred to the other molecule, causing one atom to have more/less then the other. Because there are so many atoms
When one refers to the temperature of a system, it is described as the measure of the average kinetic energy of the particles in a sample of matter. Increases in the temperature of a system results from increases in the kinetic energy of the system. The higher the temperature, the more energy atoms have, causing them to move more rapidly. In the same
This lab observed the Law of Energy Conservation that all the energy in the reactions was from the reactants breaking and forming new bonds. The Law of Energy Conservation was also observed when the energy lost as heat from the beaker was found in the calorimeter. In the calculations, Hess’ Law was tested and proved with adding the enthalpies of reaction two and three equalling the enthalpy of reaction one. This lab also observed endothermic reactions through neutralization and the forming of salts. Thermal equilibrium was observed temperature stabilizing in the calorimeter with the mixing of hot and cold water. Since the reactions were giving off heat, the enthalpy of the reactions were negative and the reactions are product
Chemical thermodynamics is the investigation of the exchange of heat and work with chemical reactions or with physical changes of state inside the bounds of the laws of thermodynamics. It involves not only laboratory measurements of different thermodynamic properties, but also the utilization of mathematical strategies to the investigation of chemical questions and the spontaneity of processes. The structure of chemical thermodynamics depends on the initial two laws of thermodynamics.
It is reasonable to suggest that just about everyone has felt the warmth of the sun or warmed themselves by a fireside, but many people may not understand the source of the energy they are feeling, particularly at the molecular level. Without heat, though, humankind would soon cease to exist and the universe would quickly collapse into an absolute zero nothingness. To gain some further insights into this essential source of life, this paper provides a review of the relevant literature to define heat and temperature, the relationship between them, and how they are different. A discussion concerning the various properties of a substance that determine its heat capacity is followed by a description of some of the various sources of heat. Finally, an analysis concerning how the study of heat relates to the kinetic theory of matter is followed by a summary of the research and important findings in the conclusion.
The feeling of warmth is a universal feeling that is caused due to heat. Heat is the transfer of thermal energy of a hotter substance to a cooler substance. Thermal energy happens to be the sum of potential energy and kinetic energy of the particles of any substance. Every object on their own has a limit to how much heat they can receive to raise the temperature of one gram by one degree, this limit is known as specific heat capacity which would be measured in J/KgºC. To calculate the thermal energy transferred during an interaction the mass(m), the change in temperature T(ºC), and the specific heat capacity(c) is needed to complete the equation.
It is the heat energy released that we are concerned with, the amount released in this reaction will provide us with the calorific value for each fuel.
HEAT 4.1 UNDERSTANDING THERMAL EQUILIBRIUM 1. Define: The measure of the degree of hotness of an object. (a) Temperature Measured in SI unit Kelvin, K A hot object is at a higher temperature than a cold object. Form of energy, measured in Joules, J (b) Heat Heat is transferred from hotter object (higher temperature) to colder object (lower temperature) When an object is heated, it will absorb heat energy and the temperature will increase. When an object is cooled, it will release heat energy and the temperature will decrease. (c) Thermal Two objects are in thermal contact when heat energy contact can be transferred between them. (d)Heat transfer When two objects with different degrees of hotness come into thermal contact, heat energy is
Purpose: You will determine the molar heat of neutralization of 1.00 M HCL and 1.00 M NaOH in Kilojoules.
State of system & state function: State of system is described in terms of T,