.) HX is used as a reagent in the reaction below. NH2 HX + :NEN: + . What functional-group transformation occurs in this reaction? 3. What is the likely identity of HX? Verify your decision with the table of Ka values in the back of your textbook. Consider the following thermodynamic data for the reaction shown above. NH2 + HX + :NEN: + 0==0

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.48P
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4.) HX is used as a reagent in the reaction below.
„NH2
+
HX
+ NEN:
+
A. What functional-group transformation occurs in this reaction?
B. What is the likely identity of HX? Verify your decision with the table of K, values in the back of your textbook.
Consider the following thermodynamic data for the reaction shown above.
„NH2
HX
+ NEN:
+
AH°¡ (kJ/mol)
-386
260.1
30.00
-393.5
S° (J/mol K)
166
146.0
191.3
191.5
213.8
C. Does the reaction absorb or release heat? Justify with a calculation.
0==0
Transcribed Image Text:4.) HX is used as a reagent in the reaction below. „NH2 + HX + NEN: + A. What functional-group transformation occurs in this reaction? B. What is the likely identity of HX? Verify your decision with the table of K, values in the back of your textbook. Consider the following thermodynamic data for the reaction shown above. „NH2 HX + NEN: + AH°¡ (kJ/mol) -386 260.1 30.00 -393.5 S° (J/mol K) 166 146.0 191.3 191.5 213.8 C. Does the reaction absorb or release heat? Justify with a calculation. 0==0
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