(0) (ii) (iii) What is the relationship between the compounds [Cl-Ag-SCN] and [SCN-Ag-CIJ? Name the compounds whose molecular formulae are given in Question 1(a) (i). Which of the compounds, [Cl-Ag-SCN] and [SCN-Ag-CI]", is the more stable? Explain your answer.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.3: Stereochemistry Of Thermal Electrocyclic Reactions
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(1)
(ii)
(iii)
(iv)
(v)
What is the relationship between the compounds [Cl-Ag-SCN]™
and [SCN-Ag-CIJ?
Name the compounds whose molecular formulae are given in
Question 1(a) (i).
Which of the compounds, [Cl-Ag-SCN] and [SCN-Ag-CI], is
the more stable? Explain your answer.
Draw the boundary surfaces of all 3d orbitals and label these
orbitals according to the conventional nomenclature. Clearly
draw and label the Cartesian axes.
Draw the crystal field splitting diagram for a linear compound,
e.g. [Cl-Ag-SCN] or [SCN-Ag-CI], aligned along the z-axis.
You only need to indicate the order of the individual d orbitals as
a function of the energy. Explain your answer.
Transcribed Image Text:(1) (ii) (iii) (iv) (v) What is the relationship between the compounds [Cl-Ag-SCN]™ and [SCN-Ag-CIJ? Name the compounds whose molecular formulae are given in Question 1(a) (i). Which of the compounds, [Cl-Ag-SCN] and [SCN-Ag-CI], is the more stable? Explain your answer. Draw the boundary surfaces of all 3d orbitals and label these orbitals according to the conventional nomenclature. Clearly draw and label the Cartesian axes. Draw the crystal field splitting diagram for a linear compound, e.g. [Cl-Ag-SCN] or [SCN-Ag-CI], aligned along the z-axis. You only need to indicate the order of the individual d orbitals as a function of the energy. Explain your answer.
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