0.0250 mol/L solution of Mn2+ is buffered with NH 3 and NH4Cl in such a way that there is no precipitation of manganous hydroxide, Mn(OH)2. Under these conditions, the concentration maximum permissible OH in the aqueous medium is ..........................mol/L. If the ammonia concentration is 0.60 mol/L, then the ammonium concentration must be at least equal to ...............mol/L, and for therefore, the mass of ammonium chloride present in the solution is equal to ....................... Data:

Fundamentals Of Analytical Chemistry
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Chapter20: Applications Of Oxidation/reduction Titrations
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0.0250 mol/L solution of Mn2+ is buffered with NH 3 and NH4Cl in such a way
that there is no precipitation of manganous hydroxide, Mn(OH)2. Under these conditions, the concentration
maximum permissible OH in the aqueous medium is ..........................mol/L. If the ammonia concentration is
0.60 mol/L, then the ammonium concentration must be at least equal to ...............mol/L, and for
therefore, the mass of ammonium chloride present in the solution is equal to ....................... Data:
KPS Mn(OH)2 = 2.0.10-13;
Kb NH3 = 1.8 x 10-5
MMNH4Cl = 53.45 g/mol. 

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