1 a. At 1280 oC, the equilibrium constant (Keq) for the reaction:  ClBr(g)  ⇔ Br(g)   +   Cl(g)  is 1.3x10-2 M.  If the initial concentrations are [ClBr] = 0.042 M, [Br] = 0.026 M, and [Cl] = 0.0 M, calculate the concentrations of these species at equilibrium. Show the algebraic expression and equilibrium concnetrations.

Chemistry & Chemical Reactivity
9th Edition
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter15: Principles Of Chemical Reactivity: Equilibria
Section: Chapter Questions
Problem 38GQ: At 2300 K the equilibrium constant for the formation of NO(g) is 1.7 103. N2(g) + O2(g) 2 NO(g)...
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1 a. At 1280 oC, the equilibrium constant (Keq) for the reaction: 

ClBr(g)  ⇔ Br(g)   +   Cl(g) 

is 1.3x10-2 M.  If the initial concentrations are [ClBr] = 0.042 M, [Br] = 0.026 M, and [Cl] = 0.0 M, calculate the concentrations of these species at equilibrium. Show the algebraic expression and equilibrium concnetrations. 

b. How many grams of phenol (C6H5OH) would you need to shift the freezing point of 100 mL water by 4.2°C?

c. Explain 4 possible changes by altering equilibrium conditions using Le Châtelier’s Principle to increase the yield of NH3 (g) in the following reaction: N2(g) + 3H2(g) ⇔ 2NH3(g) ΔH=-92Kj/mol 

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