1) Fill in the boxes and blanks below. Provide stepwise mechanisms (curved arrows) for each reaction step (elementary step) filling in all intermediates and products. Complete the Rxn Coord. Diagram template corresponding to the 2nd Rxn and ensure it represents the expected thermodynamics and kinetics expected for this reaction. (please use scratch paper first) Rxn #1 :Cl: Me a mixture Et of stereo- isomers HÖ: Me Et H-CI: :0 Me Reaction type (rxn 1)? H.. Me Rate law (rxn 1)? rate = optically pure What type of stereisomeric products (rxn 1)? intermediate 1 intermediate 2 Mes: Na CH3CN (polar solvent) Rxn #2 optically pure product Rxn type (rxn 2)? regiochemistry? ladd o & o* orbitals involved Bate law (rxn 2)? rate = rxn progress in TS for rxn 2

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.36P
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1) Fill in the boxes and blanks below. Provide stepwise mechanisms (curved arrows) for each reaction
step (elementary step) filling in all intermediates and products. Complete the Rxn Coord. Diagram template
corresponding to the 2nd Rxn and ensure it represents the expected thermodynamics and kinetics expected
for this reaction. (please use scratch paper first)
Rxn #1
:CI: Me
a mixture
Et of stereo-
isomers
Ме
Но:
:0
Et H-CI:
Ме
Reaction type (rxn 1)?
H..
Ме
Rate law (rxn 1)? rate =
optically
pure
What type of stereisomeric products (rxn 1)?
intermediate 1
intermediate 2
MeS: Na
CH3CN
(polar solvent)
Rxn
#2
E
optically pure
product
Rxn type (rxn 2)?
regiochemistry?
add o & o* orbitals involved
in TS for rxn 2
rxn progress
Rate law (rxn 2)? rate =
Transcribed Image Text:1) Fill in the boxes and blanks below. Provide stepwise mechanisms (curved arrows) for each reaction step (elementary step) filling in all intermediates and products. Complete the Rxn Coord. Diagram template corresponding to the 2nd Rxn and ensure it represents the expected thermodynamics and kinetics expected for this reaction. (please use scratch paper first) Rxn #1 :CI: Me a mixture Et of stereo- isomers Ме Но: :0 Et H-CI: Ме Reaction type (rxn 1)? H.. Ме Rate law (rxn 1)? rate = optically pure What type of stereisomeric products (rxn 1)? intermediate 1 intermediate 2 MeS: Na CH3CN (polar solvent) Rxn #2 E optically pure product Rxn type (rxn 2)? regiochemistry? add o & o* orbitals involved in TS for rxn 2 rxn progress Rate law (rxn 2)? rate =
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