1-Find the reduction potential for the couple (Cl/Cl) at pH =14? 2. Which specie(s) can go disproportionation? 3- Calculate the reduction potential E for the couple (CIO, /CIO) shown on the diagram?

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter23: Potentiometry
Section: Chapter Questions
Problem 23.23QAP: The following cell was found to have a potential of —0.492 V: Ag|AgCl(sat’d)||HA(0.200 M),NaA(0.300...
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The following Latimer diagram for Chlorine under pH = 0
+1.20
CIO,
+1.18
+1.67
+1.63
+1.36
> CIO3
→ CIO,
> CIO
+1
>Cl,
0.
> CF
-1
+7
+5
+3
E
1-Find the reduction potential for the couple (Cl/Cl) at pH =14?
2. Which specie(s) can go disproportionation?
3- Calculate the reduction potential E for the couple (CIO, /CIO) shown on the diagram?
Transcribed Image Text:The following Latimer diagram for Chlorine under pH = 0 +1.20 CIO, +1.18 +1.67 +1.63 +1.36 > CIO3 → CIO, > CIO +1 >Cl, 0. > CF -1 +7 +5 +3 E 1-Find the reduction potential for the couple (Cl/Cl) at pH =14? 2. Which specie(s) can go disproportionation? 3- Calculate the reduction potential E for the couple (CIO, /CIO) shown on the diagram?
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