1) In accordance to Crystal Field Theory (CFT): Explain in details the difference between [Fe(CN),] and [Fe(H2O)]* Atomic Number Fe=26.

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1.…

A: Ionization isomers in coordination complexes are identified by the ligands present outside the…

Q: b) For the following pair of complex ions suggest and explain which will have the strongest C=C…

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Q: Explain the ways in which the elements act: (a) How do you explain that fluoride, a small anion, is…

A: Explanation for the given parts a and b.

Q: How can know the cis and trans of geometrical isomerism in octahedral complexes?

A: Compounds have the same chemical formula but the different stereochemical structure is called…

Q: According to valence bond theory, what set of orbitals isused by a Period 4 metal ion in forming (a)…

A: a.

Q: A complex, ML62+, is violet. The same metal forms a complex with another ligand, Q, that creates a…

A: Given: The complex given is  This complex is violet. The metal gets attached to the weak field…

Q: Describe the types of NO bonds by demonstrating the electrons involved. This is an acid (pi) ligand…

A: The metal uses t2g orbital to form pi bonds with ligands. Pi star orbital of metal is high energy…

Q: <p>Many transition metal compounds are colored. How does crystal field theory account for…

A: The color of transition metal compounds is due to the absorbance of visible light. According to the…

Q: Among the following ligands, which one can behave as ambidentate ligand? Select one: a. SCN- O b.…

A: Abmidient ligand: The ambidentate ligand has two or more donor atoms, but when a complex is formed,…

Q: Apply the concept of crystal-field theory to explain some of the interesting spectral and magnetic…

A: The Crystal Field Theory (CFT) is a theory for the bonding interaction between transition metals and…

Q: Co+ +3 Pt+2

A: Applying concept of formation of 16e- and 18e- having geometries square planner and octahedral…

Q: When a hexadentate ligand, An-, binds to a metal ion that has a coordination number higher than 6,…

A:

Q: Consider the octahedral complexes of Co3+. Complete the following statements. The strong field…

A: The answer is given as follows

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1.…

A: The given condition is: Geometric isomers of anionic complexes containing hexacoordinated Os4+ and…

Q: The complexes of Fe^3+ have magnetic properties that depend onwhether the ligands are strong or weak…

A: The ligands are ranked on the basis of energy difference between the t2g and eg orbitals. When the…

Q: Both H2O and ethylenediamine (en) have two nonbonding pairs of electrons. Why can en act as a…

A:

Q: When we consider the reaction of Fe3+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: The reaction between Fe3+ and SCN- could be given as, Fe3+aq+SCN-aq→FeSCN2+ SCN- is a thiocyanate…

Q: For each of the following metals, write the electronic configurationof the atom and its 2+ ion: (a)…

A: Electronic Configuration is defined as the distribution of electrons of an atom or molecules in…

Q: Write the hybridization and shape of the following complexes: (i) [FeF6]3 (ii) [Ni(CO)4] (b) Out of…

A: Hybridization: It is a process in which atomic orbitals of same energy level (degenerate orbital)…

Q: Explain the terms diamagnetic and paramagnetic NiCl2(PPh3)2 is a green paramagnetic solid, while cis…

A: If a compound have unpaired electrons in its orbital, then the compound is known as paramagnetic in…

Q: Explain why [FeF6]³- is colorless whereas [COF6]³- is colored but exhibits only a single band in the…

A: The ligands which produces greater splitting in d orbitals are known as strong field ligands. The…

Q: The periodic trend which is responsible for the observation that the maximum oxidation state of the…

A: The periodic trend which is responsible for the observation that the maximum oxidation state of the…

Q: Draw the crystal-field energy-level diagrams and showthe placement of electrons for the following…

A: The division of d-orbitals present in central metal ion in sets of two different energies occur in…

Q: Q5 a) What are the geometric shape and the oxidation number of the copper atom, respectively, for…

A: We are given a complex of copper i.e [CuCl5]3-

Q: A complex of the type [M(AA)2X2]n+is known to be optically active. What does this indicate about the…

A: An optically active [M (AA) 2X2] n+ structure must be cis-octahedral in nature because, trans…

Q: Estimate the wavelength of maximum absorption for the octahedral ion hexacyanoferrate(III) from the…

A: Given that the light which is emitted by the solution is red, hence the solution absorbs its…

Q: 1) In accordance to Crystal Field Theory (CFT): Explain in details the difference between [Fe(CN),]*…

A:

Q: Assign oxidation states to the transition-metal ions in the following compounds: TiO2, ZrCl4, VCl3,…

A: Oxidation state indicates the degree of oxidation for an atom in a chemical compound; it is the…

Q: For each of the following metals, write the electronic configurationof the atom and its 3+ ion: (a)…

A:

Q: Construct the octahedral crystal-field splitting diagram for the metal in each species. V(H,O),*…

A:

Q: The lobes of which d orbitals point directly between the ligands in  tetrahedral geometry?

A: The four ligands will be present at the surrounding of the central  atom. Thar arrangement is…

Q: Which of these ligands can participate in linkage isomerism:(a) NO2-; (b) SO2; (c) NO3-? Explain…

A: Linkage isomerism Suppose two complexes have the same molecular formula. But their structures differ…

Q: The values for lmax for complex A and B are 512 nm and 650 nm respectively.  A has the structure…

A: Given S.No. Complex  Imax 1 [Co(NH3)4CO3]NO3 512 nm 2 [Co(NH3)4Cl2]Cl.  650 nm Explain the…

Q: 1) Why are lanthanide  complexes always weak field in nature , second and third d-transition metal…

A: Hey, since there are multiple questions posted, we will answer first question. If you want any…

Q: Metal complex A appears blue (440 nm) and complex B appears red (670 nm). Which has a larger value…

A: When a metal complex appears blue, it absorbs the complementary color orange When a metal complex…

Q: Would it be better to use octahedral complexes of Cr3+ or Co3+ to determine whether a given ligand…

A: In order to decide the strength of ligands, the following factors have to check; The electronic…

Q: Using crystal field theory, prove [NiCl4]2¯ is a tetrahedral paramagnetic complex.

A: Crystal field theory ia an electrostatic model which considers the metal-ligand bond to be ionic…

Q: 4. Using crystal field theory, prove [NiCla]²- is a tetrahedral paramagnetic complex.

A: The given complex is NiCl42-, has nickel metal as the central metal atom and the ligands are four…

Q: General questions regarding Crystal Field Theory. Use Crystal Field Splitting Diagrams as necessary.…

A:

Q: What are the examples of molybdenum complexes? In each example state the physical and chemical…

A: The some of the examples of molybdenum complexes are needed to be provided along with their physical…

Q: Explain the following terms. (i) Crystal field splitting in an octahedral field. (ii)…

A: i) In an octahedral complex, there are six ligands attached to the central transition metal.…

Q: Which of the following statement/s is/are true regarding coordination compounds? A. The interaction…

A:

Q: A complex of the type [M(AA)2X2]n+ is optically active,giving a suitable example. comment on the…

A: If the substances  which is under observation are non-superimposable mirror images of each other and…

Q: A, B, C, and D are four different ligands, draw all possible structures of geometric isomers for…

A: In square - planar complex- All the four ligand are different i.e A, B, C, and DThe complex is Pt…

Q: (a) Construct a clearly labelled molecular orbital energy level diagram for an octahedral complex…

A:

Q: What are the coordination numbers of cobalt(III), plat-inum(II), and platinum(IV) in complexes?

A: The coordination no. or ligancy of the central metal atom in a complex is defined as the total no.…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.