1 Order each of the following sets of compounds with respect to Sx2 reactivity: (a) CH3 CI H3C-C--CI CH3CH2CH2CI CH3CH2CHCH3 CH3 (b) CH3 ÇH3 ÇH3 CH3CHCHCH3 Br CH3CHCH2Br CH3CCH2B CH3 (e) CH3CH2CH2OCH3 CH3CH2CH2OTOS CH3CH2CH2Br

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 24AP
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1 Order each of the following sets of compounds with respect to Sx2 reactivity:
(a)
CH3
CI
H3C-C--CI
CH3CH2CH2CI
CH3CH2CHCH3
CH3
(b)
CH3
ÇH3
ÇH3
CH3CHCHCH3
Br
CH3CHCH2B1
CH3CCH2Br
CH3
(e) CH3CH2CH2OCH3
CH3CH2CH2OTOS
CH3CH2CH2B1
Transcribed Image Text:1 Order each of the following sets of compounds with respect to Sx2 reactivity: (a) CH3 CI H3C-C--CI CH3CH2CH2CI CH3CH2CHCH3 CH3 (b) CH3 ÇH3 ÇH3 CH3CHCHCH3 Br CH3CHCH2B1 CH3CCH2Br CH3 (e) CH3CH2CH2OCH3 CH3CH2CH2OTOS CH3CH2CH2B1
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