1- Write the Nernst equation2 for the reaction Cu2+ (aq) + Zn (s) ® Zn2+ (aq) + Cu (s) Let activity of Cu2+ equal to 1 and change the activity of Zn2+ such that Q is in the range - 0.001 to +0.001. Select different values of Q and for each calculate Ecell.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter34: Miscellaneous Separation Methods
Section: Chapter Questions
Problem 34.19QAP
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1- Write the Nernst equation2 for the reaction Cu2+ (aq) + Zn (s) ® Zn2+ (aq) + Cu (s) Let activity of Cu2+ equal to 1 and change the activity of Zn2+ such that Q is in the range - 0.001 to +0.001. Select different values of Q and for each calculate Ecell. 2- Plot Ecell-Ecelle vs In Q. What is the effect of Q (that is the activity) on Ecell-Ecelle ? Is the effect the same at higher and lower values of Q? 3- what is the largest value of the absolute difference between cell potential and standard cell potential. Ecell-Ecelle? What do you expect the graph will look like for different number of electron transferred (n )? And why? 

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