1. a) Briefly explain the physical reasoning for requiring a wavefunction to be normalized. b) The state of a harmonic oscillator is given by the wavefunction: Y(x, t=0) = A1 ¢1(x) + A2 ¢2(x). Where A1 and A2 are constants and g1(x) and o2(x) are energy eigenfunctions associated with energies E1 and E2. What condition must A1 and A2 satisfy in order for Y(x, t=0) to be normalized? c) If the particle in the state Y(x,t=0), given above, is 4 times as likely to be found having energy Ei than energy E2, find acceptable real positive values of A1 and A2 so that Y(x, t=0) satisfies this requirement and is normalized.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter5: Electron Configurations And The Periodic Table
Section: Chapter Questions
Problem 26QRT
icon
Related questions
Question
100%

Please answer all questions

(30) 1. a) Briefly explain the physical reasoning for requiring a wavefunction to be normalized.
b) The state of a harmonic oscillator is given by the wavefunction: Y(x, t=0) = A1 ¢1(x) + A2 2(x).
Where A1 and A2 are constants and ¢1(x) and 2(x) are energy eigenfunctions associated with
energies E1 and E2. What condition must A1 and A2 satisfy in order for Y(x, t=0) to be
normalized?
c) If the particle in the state Y(x,t=0), given above, is 4 times as likely to be found having energy
Ei than energy E2, find acceptable real positive values of A1 and A2 so that Y(x, t=0) satisfies this
requirement and is normalized.
d) Given Y(x,t=0) above, what is Y(x,t)? Make sure to define terms appearing in your result.
e) The time dependence of the expectation value of any operator  in an arbitrary state Y(x,t) is
given by the equation below. The equation involves the expectation value of the commutator of
the operator with the Hamiltonian and the expectation value of the partial derivative of the
operator with respect to time.
ĐÂ
a (A) = < [A,Ã] > +<>
Using this equation show that any wave function Y(x,t) that is normalized at time t=0 remains
normalized for all times t. Make sure to clearly explain your reasonings.
Transcribed Image Text:(30) 1. a) Briefly explain the physical reasoning for requiring a wavefunction to be normalized. b) The state of a harmonic oscillator is given by the wavefunction: Y(x, t=0) = A1 ¢1(x) + A2 2(x). Where A1 and A2 are constants and ¢1(x) and 2(x) are energy eigenfunctions associated with energies E1 and E2. What condition must A1 and A2 satisfy in order for Y(x, t=0) to be normalized? c) If the particle in the state Y(x,t=0), given above, is 4 times as likely to be found having energy Ei than energy E2, find acceptable real positive values of A1 and A2 so that Y(x, t=0) satisfies this requirement and is normalized. d) Given Y(x,t=0) above, what is Y(x,t)? Make sure to define terms appearing in your result. e) The time dependence of the expectation value of any operator  in an arbitrary state Y(x,t) is given by the equation below. The equation involves the expectation value of the commutator of the operator with the Hamiltonian and the expectation value of the partial derivative of the operator with respect to time. Đ a (A) = < [A,Ã] > +<> Using this equation show that any wave function Y(x,t) that is normalized at time t=0 remains normalized for all times t. Make sure to clearly explain your reasonings.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Group 2 Elements
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Modern Chemistry
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Fundamentals Of Analytical Chemistry
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:
9781285640686
Author:
Skoog
Publisher:
Cengage
Introductory Chemistry: A Foundation
Introductory Chemistry: A Foundation
Chemistry
ISBN:
9781337399425
Author:
Steven S. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning