1. Calculate pH of pure water open to the atmosphere: CO2(dissolved) + H₂O CO2(air) со 2(dissolved) + H₂O H₂CO3 H+ + HCO3* HCO3* →H+ +CO3™ -1.47 H₂CO3 KH = [H₂CO3]/PCO2 K3 = [H][ HCO3 ]/[ H₂CO3] K4 = [H][ CO3 ]/[HCO3] Given: KH=10 M/atm Pco2 = 3x10 atm -6.35 (1) (2) (3) (4) K3 = 10 Assumption: when Pco2 is not too low, [H] = [HCO3]

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
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Chapter15: Complex Ion And Precipitation Equilibria
Section: Chapter Questions
Problem 10QAP: Calculate [OH-] and pH in a solution in which the hydrogen sulfite ion, HSO3-, is 0.429 M and the...
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1. Calculate pH of pure water open to the atmosphere
CO2(dissolved) + H₂O
+ H₂O → H₂CO3
CO2(air)
CO
2(dissolved)
H₂CO3H+ + HCO3¯
H+ + CO3™
HCO3
KH = [H₂CO3]/Pc02
K3 = [H][ HCO3 ]/[ H₂CO3]
K4 = [H ][ CO3 ]/[HCO3]
Given:
-1.47
KH=10 M/atm
-4
Pco2 = 3x10 atm
-6.35
K3 = 10
Assumption: when Pco2 is not too low, [H*] = [HCO3]
Transcribed Image Text:1. Calculate pH of pure water open to the atmosphere CO2(dissolved) + H₂O + H₂O → H₂CO3 CO2(air) CO 2(dissolved) H₂CO3H+ + HCO3¯ H+ + CO3™ HCO3 KH = [H₂CO3]/Pc02 K3 = [H][ HCO3 ]/[ H₂CO3] K4 = [H ][ CO3 ]/[HCO3] Given: -1.47 KH=10 M/atm -4 Pco2 = 3x10 atm -6.35 K3 = 10 Assumption: when Pco2 is not too low, [H*] = [HCO3]
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