1. Consider the compound below for all parts to question 1. a. In the mass spectrum of this compound, three major fragmentation peaks appear (no molecular ion peak). Provide the structure and m/z value for two of them. Fragment 1: m/z = NH₂ Fragment 2: m/z = Structure: Structure: b. What peaks would you expect to see in the IR spectrum of this compound? Provide both the bond and corresponding stretching frequency for each peak outside of the fingerprint region (above 1400 cm-¹).

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter29: Mass Spectrometry
Section: Chapter Questions
Problem 29.12QAP
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1. Consider the compound below for all parts to question 1.
a. In the mass spectrum of this compound, three major fragmentation peaks appear (no
molecular ion peak). Provide the structure and m/z value for two of them.
Fragment 1: m/z =
NH₂
Fragment 2: m/z =
Structure:
Structure:
b. What peaks would you expect to see in the IR spectrum of this compound? Provide both the
bond and corresponding stretching frequency for each peak outside of the fingerprint region
(above 1400 cm-¹).
Transcribed Image Text:1. Consider the compound below for all parts to question 1. a. In the mass spectrum of this compound, three major fragmentation peaks appear (no molecular ion peak). Provide the structure and m/z value for two of them. Fragment 1: m/z = NH₂ Fragment 2: m/z = Structure: Structure: b. What peaks would you expect to see in the IR spectrum of this compound? Provide both the bond and corresponding stretching frequency for each peak outside of the fingerprint region (above 1400 cm-¹).
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