1. Consider the following mechanism: Step 1 Br₂ Step 2 Br + H₂ Step 3 H₂Br + Br a. What is the overall equation? b. Identify the intermediate(s) if any. 2Br H₂Br 2HBr fast fast slow c. What is the molecularity and the rate law for each step including any reversible steps? d. What is the predicted rate law expression for this reaction. Be sure to only list reactants from the overall equation and not intermediates in the rate law expression.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
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1. Consider the following mechanism:
Step 1
Br₂
Step 2
Br + H₂
Step 3 H₂Br + Br
a. What is the overall equation?
b. Identify the intermediate(s) if any.
2Br
H₂Br
2HBr
fast
fast
slow
c. What is the molecularity and the rate law for each step including any reversible steps?
d. What is the predicted rate law expression for this reaction. Be sure to only list
reactants from the overall equation and not intermediates in the rate law expression.
Transcribed Image Text:1. Consider the following mechanism: Step 1 Br₂ Step 2 Br + H₂ Step 3 H₂Br + Br a. What is the overall equation? b. Identify the intermediate(s) if any. 2Br H₂Br 2HBr fast fast slow c. What is the molecularity and the rate law for each step including any reversible steps? d. What is the predicted rate law expression for this reaction. Be sure to only list reactants from the overall equation and not intermediates in the rate law expression.
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