1. Determine the 1,," e" configurations and the CFSE of each of the following: (a) Mn(IV) in MnO, (Note MnO, has a rutile structure and the manganese sits in an octahedral environment of 02- ions). (b) Ni(II) – octahedral complex.

1. Determine the 1,," e" configurations and the CFSE of each of the following: (a) Mn(IV) in MnO, (Note MnO, has a rutile structure and the manganese sits in an octahedral environment of 02- ions). (b) Ni(II) – octahedral complex.

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 63AP

See similar textbooks

Related questions

Q: This question involves a calculation of the octahedral preference energy for the aqua complexes of…

A: Note: Since you have posted multiple independent questions in the same request, we will solve the…

Q: (a) A compound with formula RuCl3 . 5 H2O is dissolved inwater, forming a solution that is…

A: a.

Q: Fill in the blanks : (i) When a ligand has a two-complexing or donor group in its structure, it is…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: drow the electronic configuration of iron in heme part of hemoglobine knowing that it is a complex…

Q: Consider the following metal complexes: S. A Arrange the complexes in order of increasing stability.…

A: A question based on the strength of coordination complex, which is to be accomplished.

Q: "The magnetic properties of transition metal complexes theory". Discuss this statement fully can be…

A: In pure crystal field theory interaction between metal ions and ligands are considered as purely…

Q: Explain the ways in which the elements act: (a) How do you explain that fluoride, a small anion, is…

A: Explanation for the given parts a and b.

Q: The extent of crystal field splitting is often determined from spectra. (a) Given the wavelength…

A: As question has multiple subparts, so here solve first three subparts. If student want complete…

Q: 14. In the determination of Kf for the iron thiocyanate complex, what is the color of the complex?…

Q: Although EDTA has, in its fully protonated form, four hydrogen atoms that can be lost, it is listed…

A: The detailed solution of your question given below-- Since, we know that the structure of EDTA if we…

Q: Describe the types of NO bonds by demonstrating the electrons involved. This is an acid (pi) ligand…

A: The metal uses t2g orbital to form pi bonds with ligands. Pi star orbital of metal is high energy…

Q: 4. Magnetite, Fe304, is one of the principal mineral sources of iron, along with Haematite and…

Q: ) Define the term “ligand.” b) Give one similarity and one difference between “monodentate” and…

A: Coordination compounds are the complex that result from coordinate bond between the metal and the…

Q: b. Draw and name the structures of possible geometric and optical isomers of the cobalt complexes…

A: Isomer are those who have same molecular formula same but different structural formula. If two…

Q: The lobes of which d orbitals point directly betweenthe ligands in (a) octahedral geometry, (b)…

A: In Octahedral the ligands are pointing towards the X, Y & Z axis. The 5 d orbitals are: dxy…

Q: Consider the square base pyramidal [CuCls]3 complex. Using the provided reference system and with…

A: Let us first discuss the oxidation state and then its geometry. Finally we can draw the d orbital…

Q: a) The formation of dichlorobis(ethylenediamine)cobalt(III) nitrate is described as a Lewis…

A: SOLUTION: Step 1: (a) (i). The formation of dichlorobis(ethylenediamine)cobalt (III) nitrate is an…

Q: (a) What is the crystal field splitting energy (Δ)?(b) How does it arise for an octahedral field of…

A: a) The crystal field splitting energy is the energy difference between the two sets of d orbitals…

Q: The complexes of Fe^3+ have magnetic properties that depend onwhether the ligands are strong or weak…

A: The ligands are ranked on the basis of energy difference between the t2g and eg orbitals. When the…

Q: 3. The coordination geometries around the nickel atom in the nominally six-coordinate complexes…

Q: How do I indicate ligand charge, metal oxidation states and electron contributions from ligands/…

Q: Draw the structures and give the stock names of complexes that can satisfy the following conditions:…

Q: Draw the appropriate completely Orgel Diagram and use it to assign elctronic transition/s to any of…

Q: For each of the following metals, write the electronic configurationof the atom and its 3+ ion: (a)…

Q: The lobes of which d orbitals point directly between the ligands in tetrahedral geometry?

A: The four ligands will be present at the surrounding of the central atom. Thar arrangement is…

Q: Consider the [Ir2(dimen)4] 2+ complex. Notice that the dimen ligand is asymmetric. There is also a…

A: The two binuclear complex of Ir metal having the molecular formula [Ir2(dimen)4]2+ and [Ir2(TM4)4]2+…

Q: drow the electronic configuration of iron in heme part of hemoglobine knowing that it is a complex…

A: Hemoglobin exist in two forms oxy hemoglobin and deoxyhemoglobin. In deoxy form oxygen will not bind…

Q: he magnitude of delta octahedral (A.) epends on: he nature and charge of metal and whether the hetal…

A: The question is based on the concept of coordination compounds. We have to identify the factors on…

Q: There

A: We will identify same molecule and isomer of 1 molecule

Q: (a) How would you account for the following: (i) Highest fluoride of Mn is MnF4 whereas the highest…

A: An atom is composed of three main sub-atomic particles; electrons, neutrons and protons. The atomic…

Q: 1). What is chelate effect and why does it occur? Give an example for bidentate ligand along with…

A: When a coordination compound contains chelate ligands, then the Stability of coordination compound…

Q: Among the (pi) acid ligands of groups 15 and 16, which is the most similar, regarding the capacity…

Q: The stability of metal complexes with EDTA is due to the formation of? A) Zwitterion B) Chelate…

A: Correct Option : B) Chelate complex

Q: In a substitution reaction of an octahedral complex, the new ligands ends up in the same position as…

A: The arrangement of six ligands around the metal center at the vertices of octahedron results in the…

Q: . Explain why octahedral coordination complexes withthree and eight d electrons on the central metal…

A: The stability of the octahedral complexes can be best explained by carefully examining the…

Q: Determine the symmetry of the orbital groups for the donor sigma bonds (σ) of the ligand in an…

Q: The picture below shows one type of bonding interactions between the central metal and surrounding…

A: Crystal field theory - Crystal field theory explains the splitting of d orbitals of metal in…

Q: f)) "Crystal field theory provides a basis for explaining the features of transition metal…

A: Two statements based on coordination complexes, which are to be explained.

Q: Problem 2 norganic Compounds Determine the oxidation state of the metal in each of the following…

A: A coordination compound is a product of Lewis acid and Lewis base the ligands which have at least…

Q: Briefly define each term.. coordination number,. the ligand, bidentate, complexion, and chelating…

A: Coordination chemistry is the study of compounds that have a central atom (often metallic)…

Q: A complex of the type [M(AA)2X2]n+ is optically active,giving a suitable example. comment on the…

A: If the substances which is under observation are non-superimposable mirror images of each other and…

Q: A, B, C, and D are four different ligands, draw all possible structures of geometric isomers for…

A: In square - planar complex- All the four ligand are different i.e A, B, C, and DThe complex is Pt…

Q: The three complex ions [Mn(CN),]³-, [Mn(CN),J*¯, and [Mn(CN),]³- have all been synthesized and all…

A: All three complexes has cyanide ligand, CN- which is a strong field ligand , thus all complexes are…

Q: The (2-aminoethyl)phosphine ligand, acts as a bidentate ligand with metals of Transition. i) How…

A: The structure of (2-aminoethyl)phosphine ligand is

Q: (a) Explain the major difference between the number of oxi-dation states of most transition elements…

A: a.

Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

100%

1. Determine the t," e" configurations and the CFSE of
each of the following:
(a) Mn(IV) in MnO, (Note MnO, has a rutile structure
and the manganese sits in an octahedral environment of
02- ions).
(b) Ni(II) – octahedral complex.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

a. In the absorption spectrum of the complex ion Cr(NCS)63, there is a band corresponding to the absorption of a photon of light with an energy of 1.75 104 cm-1. Given 1 cm1 = 1.986 1023 J, what is the wavelength of this photon? b. The CrNC bond angle in Cr(NCS)63 is predicted to be 180. What is the hybridization of the N atom in the Ncs- ligand when a Lewis acid-base reaction occurs between Cr3+ and NCs- that would give a 180 CrNC bond angle? Cr(NCS)63 undergoes substitution by ethylenediamine (en) according to the equation Cr(NCS)63+2enCr(NCS)2(en)2++4NCS Does Cr(NCS)2(en)2+ exhibit geometric isomerism? Does Cr(NCS)2(en)2+ exhibit optical isomerism?
Which of the following statement(s) is( are) true? a. The coordination number of a metal ion in an octahedral complex ion is 8. b. All tetrahedral complex ions are low-spin. c. The formula for triaquatrianuninechromiwn(III) sulfate is [Cr(H2O)3(NH3)](SO4)3. d. The electron configuration of Hf2+ is [Xe]4f126s2. e. Hemoglobin contains Fe3+.
The lobes of which d orbitals point directly betweenthe ligands in (a) octahedral geometry, (b) tetrahedralgeometry?
1. Co(NH3)63+ is a low-spin complex while CoF63- is a high-spin complex. Give a rational for this difference by applying valence bond theory (i.e. illustration the hybridization and filling up of the metal orbitals). Which is the inner orbital complex and the outer orbital complex?
When we consider the reaction of Ag+ ion (SCN) with its ligand, by showing the ion-ligand bond in the product that may occur in the reaction; discuss why?
Determine the symmetry of the orbital groups for the donor sigma bonds (σ) of the ligand in an octahedral complex. Construct an MO diagram for the formation of this complex and indicate which orbitals determine the Δo. Clearly indicate the procedure.
Isn't An electron-rich transition metal has a low oxidation state, meaning that the metal centre has gained electrons from the nitrogen on NO when it coordinates as a ligand? Therefore, N-O bond length decases.
Generally speaking, for a given metal and ligand, the stability of a coordination compound is greater for the metal in the +3 rather than in the +2 oxidation state (for metals that form stable +3 ions in the first place). Suggest an explanation, keeping in mind the Lewis acid–base natureof the metal–ligand bond.