4. Magnetite, Fe304, is one of the principal mineral sources of iron, along with Haematite and Limonite. Its crystal structure corresponds to that of a spinel. a) Provide the description of the unit cell, with ion packing and occupancy of holes. (Hint: AB204) b) Assuming O? as a weak field ligand, provide the crystal field splitting diagram for each cation under each coordination environment. Clearly label the energy axis as well as all orbitals, with their correct electron occupancy.

Principles of Instrumental Analysis
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Chapter14: Applications Of Ultraviolet-visible Molecular Absorption Spectrometry
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4.
Magnetite, Fe304, is one of the principal mineral sources of iron, along with Haematite and
Limonite. Its crystal structure corresponds to that of a spinel.
a) Provide the description of the unit cell, with ion packing and occupancy of holes. (Hint: AB2O4)
b) Assuming O² as a weak field ligand, provide the crystal field splitting diagram for each cation under
each coordination environment. Clearly label the energy axis as well as all orbitals, with their correct
electron occupancy.
Transcribed Image Text:4. Magnetite, Fe304, is one of the principal mineral sources of iron, along with Haematite and Limonite. Its crystal structure corresponds to that of a spinel. a) Provide the description of the unit cell, with ion packing and occupancy of holes. (Hint: AB2O4) b) Assuming O² as a weak field ligand, provide the crystal field splitting diagram for each cation under each coordination environment. Clearly label the energy axis as well as all orbitals, with their correct electron occupancy.
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