1. Give monoborylated products for the following reactions. Include any isomers that you would expect to constitute greater than 10% of the isomer mixture. 1 equiv B2pin2 1.5 mol % [Ir(OMe)cod]2 3.0 mol % bpy -F EN CI 1 equiv B2pin2 1.5 mol % [Ir(OMe)cod]2 3.0 mol % bpy CI- -F 1 equiv B2pin2 1.5 mol % [Ir(OMe)cod]2 3.0 mol % bpy CI- -F

1. Give monoborylated products for the following reactions. Include any isomers that you would expect to constitute greater than 10% of the isomer mixture. 1 equiv B2pin2 1.5 mol % [Ir(OMe)cod]2 3.0 mol % bpy -F EN CI 1 equiv B2pin2 1.5 mol % [Ir(OMe)cod]2 3.0 mol % bpy CI- -F 1 equiv B2pin2 1.5 mol % [Ir(OMe)cod]2 3.0 mol % bpy CI- -F

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter24: Catalytic Carbon-carbon Bond Formation

Section: Chapter Questions

Problem 24.22P

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