What happens when (write reactions involved)iv and v (i) Acetophenone reacts with phenylmagnesiumbromide in presence of H20 and then product is treatedwith PC15.(ii)A cyclic organic compound A was allowed to react with NaOH+CaO to produce B which ondehydration produces C. C on ozonolysis produces D which was then oxidized to produce adioicacid with 6 carbons. Write the reactions involved and identify A, B, C and D.(iii) N-methylethanamine is treated with acetophenone and the resulting product is dehydrated(iv) Carbondioxide reacts with very limited amount of phenylmagnesiumbromide (1:1) and resultingproduct is hydrolyzed. The resulting product is treated with glycol (CH2OH-CH2OH).(v)Cyclohexene is oxidized with acidified KMNO4 and the product is treated with 1,2-ethandiol

Since you have posted a question with multiple sub parts, we will solve last two sub parts for you,…

Answered: What happens when (write reactions…

Science

Chemistry

What happens when (write reactions involved) iv and v

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter23: Amines

Section: Chapter Questions

Problem 23.58P

See similar textbooks

Related questions

Q: Give the product for the following reaction. 1. H2NNH2 2 N2OH, Heat OH NH NH2 NH2 N.

A: The given reaction of ketone with hydrazine (H2NNH2) is the Wolff-Kishner Reduction reaction. This…

Q: a) Find the maximum amount of X (g) that can be dissolved in 100 g of water at 50°C (. b) Calculate…

A: a) From the graph, it is clearly observed that 160 g(approx) be the maximum amount of the X(s) can…

Q: 11. Tannins which present in tea leaves can be converted into water soluble salts by : a. Gentle…

A: Tannins which present in tea leaves can be converted into water soluble salts by the addition of…

Q: Calculate the heat of reaction deltaH for the following reaction: 2CH4(g)+3O2(g)——>2CO(g)+ 4H2O(g)…

A: Given 2CH4(g)+3O2(g) → 2CO(g)+ 4H2O

Q: Consider a mixture of the compounds shown below dissolved in hexane (C,H;a) CH3(CH)10CH3 CH,COOH…

A: Note: According to our guidelines we are supposed to answer only one question. Kindly repost other…

Q: Consider the reaction scheme below. N Br₂ FeBr3 NaOH warm X AICI 3 Y CI

Q: 1. a. Use Hess's law and the measured mean enthalpy changes for the NaOH-HCl and NH3-HCl reactions…

A: The target reaction is as below: NaOH + NH4Cl ----> NaCl + NH3 + H2O Its enthalpy change using…

Q: Ethanol and KCl both dissolve in water. What happens 90 to the ionic bond when KCl dissolves? What…

A: Given information, Ethanol and KCl dissolves in water. KCl is an ionic compound and…

Q: What is the enthalpy for reaction 1 reversed? reaction 1 reversed: 2NO + O2→2NO2

A: Please find your solution below : The enthalpy of any reaction is calculated through the following…

Q: dissociation of H2CO3 to H20 and CO2

A: Dissociation is ability to break into smaller groups.

Q: 1 way you could increase how quickly you could dissolve 0.5g of carbon dioxide gas into 100g of…

Q: The disinfection of drinking water to control microbial contaminants can form chemical disinfection…

A: At boiling point of any liquid, its vapor pressure equals to atmospheric pressure. T1 = Tb = 213 C =…

Q: What is the heat, q, when 25.0 g of acetonitrile, CH3CN, reacts completely with an excess of water?…

A: Using molar mass of CH3CN and from given data we can find heat (q).

Q: Which of the following compounds is most soluble in water? O CH3CH2OH O CH3CH3 O…

A: Solublity depend on the nature of solvent and solute. We have a concept of like dissolve like that…

Q: Is butanedioic acid soluble in water? HCl? NaOH? NaHCO3?

A: butanedioic acid is another name for succinic acid

Q: Study the reactions. 1. C2H2 (g) + 2H2 (g) → C2H6 (9) 2. C2H4 (9) + H2 (g) → C2H6 (9) 3. C2H2 (g) +…

Q: For the reaction - what effect would adding large amounts of heat have on the equilibrium? (Which…

A: Le-Chatelier's principle deals with the shifting of equilibrium (left or right) of the reaction with…

Q: reaction has a standard free-energy change of -15.50 kJ mol-1 (3.776 kcal mol-1 ) Calculate the…

A: ∆G°=-RTlnKequi. ∆G°= -15000 Jmol-1 T=25+273= 298K

Q: Consider the reaction: N2(g) + 3H2(g) --> 2NH3(g) where ΔH = -15.0 kcal/mol and ΔS =…

A: Given reaction; N2(g) + 3H2(g) --> 2NH3(g) where, ∆H = -15.0 Kcal/mol and, ∆S = -35.0 cal/mol.K…

Q: Are purified aspirin crystals more soluble in hot water or in vinegar?

A: The aspirin is more soluble in which solvent is given below with explanation.

Q: MCQ 48: Catalysts speed up reactions but when equilibrium is reached it has A. huge effect B. no…

A: Given options are,

Q: 2 Ba2+ (aq) + Cr20,2 (aq) + H2O (1) =2 BaCrO4 (s) + 2 H* (aq) Dichromate forms orange aqueous…

A: The equilibrium reaction given is,

Q: Arrange the following compounds in order of increasing vapor pressure. NH PH A C

A: A question based on physical properties, which is to be accomplished.

Q: Tell whether each reaction favors product-formation or reactant-formation. A. 2NO) + O2e)= 2NO2) K,…

A: We write partial pressures of gaseous products and gaseous reactants in the expression of Kp.

Q: 0, „OtBu -OtBu HN CO,Me 1. LDA 2. N. OMe SO-Ph 3. aqueous workup

Q: Rank the following in terms of increasing melting point: MgCl2 NaCl AlCl3

A: Melting point: It is the point at which the solid substance starts changing its state to liquid. The…

Q: ....OH

A: all the reactions following different mechansims

Q: Q26(B)(b)

A: We will use formula of molality

Q: how can non-beneficial chemical reactions be minimized or stopped ?

A: how can non-beneficial chemical reactions be minimized or stopped ? Explanation is given below.

Q: 1. In energy diagram 1, R represents the reactants and Pj and P2 the products. Which product would…

Q: N,N-Dimethyltryptamine (DMT) is a powerful hallucinogenic that is being trialled (in low doses) to…

A: The given molecule, DMT is highly non-polar and hence very less soluble in the bloodstream and gut.

Q: The dissolution of NH,Cl in water is an endothermic process. If the initial temperature of water is…

A: Endothermic reaction is reaction in which energy/heat is consume in reaction.

Q: Why is benzoic acid insoluble in water while sodium benzoate is soluble? How are their chemical…

A: Since, you have asked multiple questions, we will solve the first question for you. Benzoic acid…

Q: Consider the explanation in the Introduction regarding the determination of qrxn, and answer the…

A: A) Given: The temperature of HCl solution increases.

Q: 2 NO2 = N2O4 + heat IN THE ABOVE REVERSIBLE REACTION, WHEN HEAT IS INCREASED, WHICH DIRECTION WILL…

A: Given reversible reaction is: 2NO2 ⇌ N2O4 +heat In which direction does the equilibrium shift if…

Q: The standard free energy change for the reaction CH4(g)+2O2(g) -> CO2(g) + 2H2O(l) is -194.8 kcal at…

Q: Arrange the following sets of organic compounds according to decreasing solubility in water I.…

A: Alcohol can be defined as an organic compound in which carbon atom is attached to hydroxyl group.

Q: 10. A total of 1.7 moles of sodium nitrate is dissolved in enough water 1 poin to make 2.5 liters of…

Q: Calculate the heat of reaction deltaH for the following reaction: CH4(g)+2O2(g)——> CO2(g) + 2H2O(g)…

Q: How many calories will be needed to completely evaporate 5.0 kilograms of water that is 100 oC? 2.7…

A: The latent heat of vaporization of water is 2230 J/g or 533 calories per gram.

Q: C H O You have your choice of sucrose, 12*2211, sodium chloride, NaCl or cal- CaCl 2 to use to melt…

A: Solution is defined as the homogenous mixture that consists of solute and solvent. The substance…

Q: 7. During bot summer months, high altitude lakes are more susceptible to "fish kills" (where all of…

A: Solubility depends on altitude and temperature as high altitudes means less pressure low solubility…

Q: Arrange the following compounds from most soluble to least soluble in water. I. methanol II.…

A: A solubility of alcohols in water mainly depends on hydrogen bonding between water. As hydrogen…

Q: Ethanol and KCl both dissolve in water. what happens to the ionic bond when KCl dissolves? What…

A: Ethanol is a polar compound and KCl is an ionic compound when KCl is dissolved in water, KCl…

Q: solute Which is the better solvent? :0: CH,-S. CH3 :0: :0: - НО — С — СН, — СН, — С — он CH,CH,OH…

A: The solubility of a solute in a particular solvent depends on the nature of the solute and the…

Q: explain why on addition of 1 mol of NaCl to 1 litre of water, the boiling point of water increases,…

A: NaCl is a non-volatile solute, therefore, addition of NaCl to water lowers the vapour pressure of…

Q: What is the value of Ke in boiling water? a) Ke > 1 c) K. << 1 d) Ke = 1

A: The equilibrium constant Kc is the ratio of the equilibrium concentrations of products over the…

Q: SiO₂(s) + 4HF(g) SiF4(g) + 2H₂O(g) ect on [SiF4] when (a) H₂O(g) is removed; (b) some liquid water…

A: Equilibrium is affected by the change in pressure, volume and temperature which are determined by…

Q: 5) If 1 CN- ion kills 10 cancer cells, how many cells would be killed by drinking 25 ml of a…

A: Solubility product is expressed for sparingly soluble salt and Ksp is product of concentration of…

Question

What happens when (write reactions involved) iv and v

(i) Acetophenone reacts with phenylmagnesiumbromide in presence of H20 and then product is treated
with PC15.
(ii)A cyclic organic compound A was allowed to react with NaOH+CaO to produce B which on
dehydration produces C. C on ozonolysis produces D which was then oxidized to produce a
dioicacid with 6 carbons. Write the reactions involved and identify A, B, C and D.
(iii) N-methylethanamine is treated with acetophenone and the resulting product is dehydrated
(iv) Carbondioxide reacts with very limited amount of phenylmagnesiumbromide (1:1) and resulting
product is hydrolyzed. The resulting product is treated with glycol (CH2OH-CH2OH).
(v)Cyclohexene is oxidized with acidified KMNO4 and the product is treated with 1,2-ethandiol

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Compound A has the molecular formula C14H25Br and was obtained by reaction of sodium acetylide (HC≡CNa) )with 1,12-dibromododecane. On treatment of compound A with sodium amide, it was converted to compound B (C14H24). Ozonolysis of compound B gave the diacid HO2C(CH2)12CO2H. Catalytic hydrogenation of compound B over Lindlar palladium gave compound C (C14H26), while hydrogenation over platinum gave compound D (C14H28). Sodium-ammonia reduction of compound B gave compound E (C14H26). Both C and E yielded O═CH(CH2)12CH═O on ozonolysis. Assign structures to compound A through E so as to be consistent with the observed transformations.
Compound A has the molecular formula C14H25Br and was obtained by thereaction of sodium acetylide with 1,12-dibromododecane. On treatment ofcompound A with sodium amide, compound B (C14H24) was obtained. Ozonolysisof compound B gave the diacid HO2C(CH2)12CO2H. Catalytic hydrogenation ofcompound B over Lindlar palladium gave compound C (C14H26), andhydrogenation over platinum gave compound D (C14H28). Further, C yieldedO=CH(CH2)12CH=O on ozonolysis. Assign structures to compounds A through Dso as to be consistent with the observed transformations.
When pyrrole is added to a dilute solution of D2SO4 in D2O, 2-deuteriopyrrole is formed. Propose a mecha-nism to account for the formation of this compound.
Compound EE, C5H10O gives a positive result (formation of silver mirror) when reacted with Tollen’s reagent. Reduction of EE with sodiumborohydride, NaBH4 followed by acidified water, H3O+ produces compound FF. Dehydration of compound FF uses concentrated sulphuric acid, H2SO4 at a temperature of 180°C produces compound GG. Compound FF also reacts with hot acidified potassium dichromate, K2Cr2O7 to produce 2-methylbutanoic acid, C4H9COOH. Esterification between 2-methylbutanoic acid and methanol, CH3OH produces compound HH. Draw the structural formula of compounds EE, FF, GG, and HH.
Two moles of organic compound ‘A’ on treatment with a strong base gives two compounds ‘B’ and ‘C’. Compound ‘B’ on dehydrogenation with Cu gives ‘A’ while acidification of ‘C’ yields carboxylic acid ‘D’ with molecular formula of CH2O2. Identify the compounds A, B, C and D and write all chemical reactions involved.
3. Obtain acetophenone and acetaldehyde by reaction of glycols with periodic acid. Justify your answer with the reaction mechanism.
Describe the ozonolysis of alkenes one mole of a hydrocarbon(A) reacts with one mole of beomine giving a dibromo compound C5H10Br2.Substance A on treatment with cold dilute kMnO4 solution forms a compound C5C12O2(C5H12O2) on ozonolysis A,gives equimolar quantities of propanone and ethanol.Deduce the structure of substance A.
Give a rearrangement reaction equation to synthesize N-ethyl-2-methyl-buthylamide from the corresponding α-diazoketone. Give the structures of all intermediary products. Do not give a mechanism.
Stearolic acid, C18H32O2, yields stearic acid on catalytic hydrogenation and undergoes oxidative cleavage with ozone to yield nonanoic acid and nonanedioic acid. What is the structure of stearolic acid?
In an aqueous solution containing sodium bicarbonate, aniline reacts quickly withbromine to give 2,4,6-tribromoaniline. Nitration of aniline requires very strong conditions,however, and the yields (mostly m-nitroaniline) are poor.(a) What conditions are used for nitration, and what form of aniline is present under theseconditions?
Two isomers, A and B, of molecular formula C5H8 undergo catalytic hydrogenation with hydrogen gas and palladium on carbon to form the same C5H10 product. On ozonolysis followed by treatment with hydrogen peroxide (H2O2), isomer A gave a product of molecular formula C5H8O4 that has two carboxylic acid groups in it whereas isomer B gave a product of molecular formula C5H8O3 that contains a carboxylic acid group and a ketone group. Which of the following isomeric pairs best match this data?
Two isomers, A and B, of molecular formula C5H8 undergo catalytic hydrogenation with hydrogen gas and palladium on carbon to form the same C5H10 product. On ozonolysis followed by treatment with hydrogen peroxide (H2O2), isomer A gave a product of molecular formula C5H8O4 that has two carboxylic acid groups in it whereas isomer B gave a product of molecular formula C5H8O3 that contains a carboxylic acid group and a ketone group. What is the isometric pair of A and B that corresponds?