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1. Give the products of the acid-base reactions below and indicate whether products or reagents would be favored a. CH3CO2 CF3CH2OH t b. H3N CH30 Na* H2N NH3 C. НАР* d. H3N H4C CH3 C C е. f. H30 NH3 CH3CO2H g. H20 h. H20 H2S 2. Draw the most stable conjugate acid for each of the three heterocycles below. Of these three nitrogen heterocycles, which is the least basic? Which is the most basic? H Н H H N H нн H 3. Which atoms in the following structures have the greatest partial negative charge Нас Нзс OCH2CH2CCF2CF2CF20 HNO NH2 NH . 4. Which of the following is most acidic? D C B A "C(CH)з (H3C)3C CH3 Hас N. CF3CF3 H3C CH3 Hас" "CНз z. I CD :Z I Z-I

1. Give the products of the acid-base reactions below and indicate whether products or reagents would be favored a. CH3CO2 CF3CH2OH t b. H3N CH30 Na* H2N NH3 C. НАР* d. H3N H4C CH3 C C е. f. H30 NH3 CH3CO2H g. H20 h. H20 H2S 2. Draw the most stable conjugate acid for each of the three heterocycles below. Of these three nitrogen heterocycles, which is the least basic? Which is the most basic? H Н H H N H нн H 3. Which atoms in the following structures have the greatest partial negative charge Нас Нзс OCH2CH2CCF2CF2CF20 HNO NH2 NH . 4. Which of the following is most acidic? D C B A "C(CH)з (H3C)3C CH3 Hас N. CF3CF3 H3C CH3 Hас" "CНз z. I CD :Z I Z-I

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter11: Ethers, Epoxides, And Sulfides
Section: Chapter Questions
Problem 11.42P
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1. Give the products of the acid-base reactions below and indicate whether products or reagents would be favored a. CH3CO2 CF3CH2OH t b. H3N CH30 Na* H2N NH3 C. НАР* d. H3N H4C CH3 C C е. f. H30 NH3 CH3CO2H g. H20 h. H20 H2S 2. Draw the most stable conjugate acid for each of the three heterocycles below. Of these three nitrogen heterocycles, which is the least basic? Which is the most basic? H Н H H N H нн H 3. Which atoms in the following structures have the greatest partial negative charge Нас Нзс OCH2CH2CCF2CF2CF20 HNO NH2 NH . 4. Which of the following is most acidic? D C B A "C(CH)з (H3C)3C CH3 Hас N. CF3CF3 H3C CH3 Hас" "CНз z. I CD :Z I Z-I
Transcribed Image Text:1. Give the products of the acid-base reactions below and indicate whether products or reagents would be favored a. CH3CO2 CF3CH2OH t b. H3N CH30 Na* H2N NH3 C. НАР* d. H3N H4C CH3 C C е. f. H30 NH3 CH3CO2H g. H20 h. H20 H2S 2. Draw the most stable conjugate acid for each of the three heterocycles below. Of these three nitrogen heterocycles, which is the least basic? Which is the most basic? H Н H H N H нн H 3. Which atoms in the following structures have the greatest partial negative charge Нас Нзс OCH2CH2CCF2CF2CF20 HNO NH2 NH . 4. Which of the following is most acidic? D C B A "C(CH)з (H3C)3C CH3 Hас N. CF3CF3 H3C CH3 Hас" "CНз z. I CD :Z I Z-I
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