What reagents would you use to prepare product A with good yield? ? CH3C=CH A O a 1) CH3CH2CH2CH2l: 2) Li, NH3 (liq), -33 °C Ob. 1) HBr; 2) (CH3CH2CH2CH2)2CULI Oc1) KNH2 2) CH3: 3) H2. Pd/C Od. 1) (CH3CH2CH2CH2)2CULI; 2) H2, Lindlar catalyst Oe 1) NANH2: 2) CH3CH2CH2CH2Br, 3) H2. Lindlar catalyst

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...
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What reagents would you use to prepare product A with good yield?
?
CH3C=CH
A
a. 1) CH3CH2CH2CH21; 2) Li, NH3 (lig), -33 °C
b. 1) HBr; 2) (CH3CH2CH2CH2)2Culi
O. 1) KNH2; 2) CH31; 3) H2, Pd/C
Od. 1) (CH3CH2CH2CH2)2CuLi; 2) H2, Lindlar catalyst
Oe. 1) NANH2: 2) CH3CH2CH2CH2Br, 3) H2, Lindlar catalyst
Which substance in each of the following pairs will make a SN2 reaction
go faster?
1) acetonitrile (CH3CN) or methanol as solvent
2) CH3CH2CH2CH2I or CH3CH2CH2CH2CI as substrate
3) H20 or OH¯ as nucleophile
4) CH3CH2CH2CH2Br or (CH3)3CB as substrate
5) BRCH=CHCH2CH3 or BrCH2CH=CH2CH3 as substrate
a. 1) methanol, 2) CH3CH2CH2CH2CI, 3) H20, 4) (CH3)3CBT, 5) BrCH=CHCH2CH3
O b.1) CH3CN, 2) CH3CH2CH2CH2CI, 3) H20, 4) (CH3)3CBT, 5) BrCH2CH=CH2CH3
O. 1) CH3CN, 2) CH3CH2CH2CH21, 3) OH", 4) CH3CH2CH2CH2Br, 5) BRCH2CH=CH2CH3
O d. 1) CH3CN, 2) CH3CH2CH2CH21, 3) OH", 4) CH3CH2CH2CH2Br, 5) BRCH=CHCH2CH3
е.
1) methanol, 2) CH3CH2CH2CH21 , 3) OH", 4) CH3CH2CH2CH2Br, 5) BRCH=CHCH2CH3
Transcribed Image Text:What reagents would you use to prepare product A with good yield? ? CH3C=CH A a. 1) CH3CH2CH2CH21; 2) Li, NH3 (lig), -33 °C b. 1) HBr; 2) (CH3CH2CH2CH2)2Culi O. 1) KNH2; 2) CH31; 3) H2, Pd/C Od. 1) (CH3CH2CH2CH2)2CuLi; 2) H2, Lindlar catalyst Oe. 1) NANH2: 2) CH3CH2CH2CH2Br, 3) H2, Lindlar catalyst Which substance in each of the following pairs will make a SN2 reaction go faster? 1) acetonitrile (CH3CN) or methanol as solvent 2) CH3CH2CH2CH2I or CH3CH2CH2CH2CI as substrate 3) H20 or OH¯ as nucleophile 4) CH3CH2CH2CH2Br or (CH3)3CB as substrate 5) BRCH=CHCH2CH3 or BrCH2CH=CH2CH3 as substrate a. 1) methanol, 2) CH3CH2CH2CH2CI, 3) H20, 4) (CH3)3CBT, 5) BrCH=CHCH2CH3 O b.1) CH3CN, 2) CH3CH2CH2CH2CI, 3) H20, 4) (CH3)3CBT, 5) BrCH2CH=CH2CH3 O. 1) CH3CN, 2) CH3CH2CH2CH21, 3) OH", 4) CH3CH2CH2CH2Br, 5) BRCH2CH=CH2CH3 O d. 1) CH3CN, 2) CH3CH2CH2CH21, 3) OH", 4) CH3CH2CH2CH2Br, 5) BRCH=CHCH2CH3 е. 1) methanol, 2) CH3CH2CH2CH21 , 3) OH", 4) CH3CH2CH2CH2Br, 5) BRCH=CHCH2CH3
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