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A:
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Q: но NBS HBr ether CCI, a. b. Mg, ether SOCI, Br H,0 d.
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Q: 9. C,H¿O (Propanone) 10. C,H10 11. C,H,OH (Isopropanol) 12. C,H1,0 (Pentanone)
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Q: Name each disubstituted benzene. Br b. CH;-CH3 a. с. CI `CH;-CH3 Br
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Q: H6 (benzene) CHSCI (chlorobenzene) Br CHSB (bromobenzene) OH C,H,OH (phenol, or hydroxybenzene)
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Q: Which substitution reaction takes place more rapidly?
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Q: (CH3CO)20 Br2 a.) H2N- CH3 pyridine FeBr3 1. LIAIH4, ether 2. Но b.) NaN3 Br c.) H2/Ni + -NH2
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Q: Give iupac name for this diol CH3CH(OH)(CH2)4CH(OH)C(CH3)3
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Q: 1. Please, name the following compounds according to IUPAC rules. OCH, OH b) c) HOOC .COOH COOH Br…
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A: A) Double bonds except aromaticity.
Q: 9. C,HO (Propanone) 10. C,H10 11. С, Н,Он (Isopropanol) 12. C,H,,0 (Pentanone)
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Q: 1. Please, name the following compounds according to IUPAC rules. OCH3 OH b) c) HOOC .COOH СООН Br…
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Q: Which of these is an ether? A) B) CH3 FOH OH C) D) E) F) "CH3 IZ
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Q: Name each compound. CH,CH3 A. CH,CH3 CI B.
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- (−)-Hyoscyamine, an optically active drug used to treat gastrointestinal disorders, is isolated from Atropa belladonna, the deadly nightshade plant, by a basic aqueous extraction procedure. If too much base is used during isolation, optically inactive material is isolated. (a) Explain this result by drawing a stepwise mechanism. (b) Explain why littorine, an isomer isolated from the tailflower plant in Australia, can be obtained optically pure regardless of the amount of base used during isolation.Interestingly, reduction of the complex shown above mostly gives thealcohol enantiomer shown below after workup. a. Draw the other minor diastereomeric alcohol product. b. Briefly explain the diastereoselectivity of the reduction – why is oneenantiomer heavily favored? Draw a structure or structures to support youranswer.A key step in the synthesis of β-vetivone, a major constituent of vetiver, a perennial grass found in tropical and subtropical regions of the world, involved the reaction of compound A and dihalide B with two equivalents of LDA to form C. Draw a stepwise mechanism for this reaction. β-Vetivone contains a spiro ring system—that is, two rings that share a single carbon atom.
- Explain the E2 mechanism (bimolecular elimination) of of Elimination ?Draw a stepwise mechanism for the following Robinson annulation. This reaction was a key step in a synthesis of the steroid cortisone by R. B. Woodward and co-workers at Harvard University in 1951.One step in the synthesis of the nonsteroidal anti-inammatory drug rofecoxib (trade name Vioxx) involves Suzuki coupling of A and B. What product is formed in this reaction?
- Do not give handwriting solution. please draw out what compound A is and then provide aroow pushing mechanism for thisreaction! thanks01 Cive the ctrientiono of Comnand 4 2.2 Provide a reasonable arrowpushing mechanism for the reaction in 2.1Suzuki coupling of aryl iodide A and vinylborane B affords compound C, which is converted to D in the presence of aqueous acid. Identify compounds C and D and draw a stepwise mechanism for the conversion of C to D.Treatment of α,β-unsaturated carbonyl compound X with base forms the diastereomer Y. Write a stepwise mechanism for this reaction. Explain why one stereogenic center changes conguration but the other does not.
- What product is formed when each compound undergoes anintramolecular reaction in the presence of acid?Hydroxy aldehydes A and B readily cyclize to form hemiacetals. Draw thestereoisomers formed in this reaction from both A and B. Explain whythis process gives an optically inactive product mixture from A and anoptically active product mixture from B.The sex pheromone (matsuone) of a parasitic insect (Matsucoccus) that infests pine trees was prepared in a multistep synthesis from (−)-citronellol by way of the nitrile shown.(a) Relate the nitrile to (−)-citronellol by a retrosynthetic analysis. (b) Convert your retrosynthesis to a synthesis, showing appropriate reagents for each step.Identify compounds A and B, two synthetic intermediates in the 1979 synthesis of the plant growth hormone gibberellic acid by Corey and Smith. Gibberellic acid induces cell division and elongation, thus making plants tall and leaves large.