1. Prelimanry Study Sulfamic acid is a strong acid. Write the equation of its reaction with water. List the appropriate material needed to : 1.1- 1.2- o Weigh the mass m of 2.05 g; - add the sodium hydroxide solution. o Take the volume Va; - prepare the volume V ; 1.3- Write the equation of the titration reaction of sulfamic acid. Based on the chemical species present in solution at equivalence, justify the pH value of 7 found at equivalence. 1.4- 2. Make-use of the result of the titration

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Available is a white powdered descaling agent containing solid sulfamic acid.
The aim of this exercise is to determine the percent composition by mass of sulfamic acid in this descaling
agent.
Given :
sulfamic acid, of formula NH2SO3H, is denoted by HA in this exercise.
Molar mass of sulfamic acid in g.mol: M = 97.1
Experimental Procedure :
-First step: a mass m = 2.05 g of this descaling agent is disolved in distilled water in order to obtain a
solution (S) of volume V = 500 mL.
-Second step : a volume Va = 10 mL of the solution (S) is poured into a beaker. Then a volume V´ of
distilled water is added in order to immerse properly the pH-meter electrode.
- Third step : the pH metric titration is carried out using a sodium hydroxide solution of
concentration C = 4,0x10² mol.L!.
1. Prelimanry Study
Sulfamic acid is a strong acid. Write the equation of its reaction with water.
List the appropriate material needed to :
1.1-
1.2-
Weigh the mass m of 2.05 g ; - add the sodium hydroxide solution.
o Take the volume Va;
- prepare the volume V ;
Write the equation of the titration reaction of sulfamic acid.
Based on the chemical species present in solution at equivalence, justify the pH value of 7
found at equivalence.
1.3-
1.4-
2- Make-use of the result of the titration
Given below, some of the results of the titration:
Vb (mL)
10.4
15
pH
plot the shape of the curve pH = f(Vb) for 0 < Vb< 15 mL. Take the following scales:
In abscissa: 1cm for 1mL,
In ordinates: 1 cm for 1 pH unit.
Determine the concentration Ca of the sulfamic acid solution (S).
2.4
7.0
11.0
2.1-
2.2-
2.3-
Deduce the percent mass composition of sulfamic acid in this descaling agent.
3- Effect of dilution on the pH metric study
A solution (S) of descaling agent is prepared by diluting 10 times the solution (S).
3.1.Choose, by justifying, among the following sets, the most precise one needed to carry out the
required dilution.
Set -1
Set – 2
Set – 3
10 mL Volumetric pipet
10 mL graduated
сylinder
200 mL volumetric flask
10 mL Volumetric pipet
100 mL Beaker.
100 mL volumetric
flask.
Transcribed Image Text:Available is a white powdered descaling agent containing solid sulfamic acid. The aim of this exercise is to determine the percent composition by mass of sulfamic acid in this descaling agent. Given : sulfamic acid, of formula NH2SO3H, is denoted by HA in this exercise. Molar mass of sulfamic acid in g.mol: M = 97.1 Experimental Procedure : -First step: a mass m = 2.05 g of this descaling agent is disolved in distilled water in order to obtain a solution (S) of volume V = 500 mL. -Second step : a volume Va = 10 mL of the solution (S) is poured into a beaker. Then a volume V´ of distilled water is added in order to immerse properly the pH-meter electrode. - Third step : the pH metric titration is carried out using a sodium hydroxide solution of concentration C = 4,0x10² mol.L!. 1. Prelimanry Study Sulfamic acid is a strong acid. Write the equation of its reaction with water. List the appropriate material needed to : 1.1- 1.2- Weigh the mass m of 2.05 g ; - add the sodium hydroxide solution. o Take the volume Va; - prepare the volume V ; Write the equation of the titration reaction of sulfamic acid. Based on the chemical species present in solution at equivalence, justify the pH value of 7 found at equivalence. 1.3- 1.4- 2- Make-use of the result of the titration Given below, some of the results of the titration: Vb (mL) 10.4 15 pH plot the shape of the curve pH = f(Vb) for 0 < Vb< 15 mL. Take the following scales: In abscissa: 1cm for 1mL, In ordinates: 1 cm for 1 pH unit. Determine the concentration Ca of the sulfamic acid solution (S). 2.4 7.0 11.0 2.1- 2.2- 2.3- Deduce the percent mass composition of sulfamic acid in this descaling agent. 3- Effect of dilution on the pH metric study A solution (S) of descaling agent is prepared by diluting 10 times the solution (S). 3.1.Choose, by justifying, among the following sets, the most precise one needed to carry out the required dilution. Set -1 Set – 2 Set – 3 10 mL Volumetric pipet 10 mL graduated сylinder 200 mL volumetric flask 10 mL Volumetric pipet 100 mL Beaker. 100 mL volumetric flask.
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