1. The following melting point data were obtained for a series of pure compounds and mixtures. Based on the observed melting points (mp), what is the identity of the unknown compound? Compound Observed mp Compound Observed mp acetamide 81°C unknown 131°-135°C acetanilide 113°-115°C mixture of unknown trans-cinnamiç acid 133°C hippuric acid succinimide thiourea and urea 105°-130°C 187°-188°C mixture of unknown and cinnamic acid mixture of unknown and succinimide 125°-127°C 133°-134°C 176°-178°C urea 132.7°C 100°-125°C

Organic Chemistry
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ISBN:9781305080485
Author:John E. McMurry
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Chapter21: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions
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1. The following melting point data were obtained for a series of pure compounds
and mixtures. Based on the observed melting points (mp), what is the identity
of the unknown compound?
Compound
Observed mp
Compound
Observed
mp
acetamide
acetanilide
81°C
unknown
131°-135°C
113°-115°C
mixture of unknown
trans-cinnamic acid 133°C
hippuric acid
succinimide
thiourea
and urea
105°-130°C
187°-188°C
mixture of unknown
and cinnamic acid
mixture of unknown
125°-127°C
133°-134°C
176°-178°C
132.7°C
and succinimide
100°-125°C
urea
Unknown?
Transcribed Image Text:1. The following melting point data were obtained for a series of pure compounds and mixtures. Based on the observed melting points (mp), what is the identity of the unknown compound? Compound Observed mp Compound Observed mp acetamide acetanilide 81°C unknown 131°-135°C 113°-115°C mixture of unknown trans-cinnamic acid 133°C hippuric acid succinimide thiourea and urea 105°-130°C 187°-188°C mixture of unknown and cinnamic acid mixture of unknown 125°-127°C 133°-134°C 176°-178°C 132.7°C and succinimide 100°-125°C urea Unknown?
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