1. Use the following data for NH3 (g) at T= 273 K to evaluate B2p(T). (Here Z is the compressibility factor, PV/RT). P (bar) Z-1 0.10 1.519 x 10-4 0.20 3.038 x 10-4 0.30 4.557x 104 0.40 6.071 x 10-4 0.50 7.583 x 104 0.60 9.002 x 10-4 0.70 1.0551 x 10-3 Hint: You will need to fit this data to a least-squares line, which can be done most easily in either Excel or in WolframAlpha.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter12: Thermodynamic Processes And Thermochemistry
Section: Chapter Questions
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question 1 plese,little help..

1. Use the following data for NH3 (g) at T= 273 K to evaluate B2p(T). (Here Z is the
compressibility factor, PV/RT).
P (bar)
Z-1
0.10
1.519 x 10-4
0.20
3.038 x 10-4
0.30
4.557x 10-4
0.40
6.071 x 10-4
0.50
7.583 x 10-4
0.60
9.002 x 10-4
0.70
1.0551 x 10-3
Hint: You will need to fit this data to a least-squares line, which can be done most easily in
either Excel or in WolframAlpha.
2. The molar heat capacities for solid, liquid, and gaseous molecular chlorine can be written in
the following general form, where the coefficients a, b, c and d are given in the table below.
Cp°
= a + bT + cT2 + dT3
T Range (in K)
b (in K-1)
c (in K-2)
d (in K-3)
a
Phase
15 - 172.12
-1.545
0.1502
-0.001179
3.441 x 10-6
solid
172.12-239.0
7.689
0.005582
- 1.954 x 104
liquid
> 239.0
3.812
0.001220
-4.856 x 10-7
Transcribed Image Text:1. Use the following data for NH3 (g) at T= 273 K to evaluate B2p(T). (Here Z is the compressibility factor, PV/RT). P (bar) Z-1 0.10 1.519 x 10-4 0.20 3.038 x 10-4 0.30 4.557x 10-4 0.40 6.071 x 10-4 0.50 7.583 x 10-4 0.60 9.002 x 10-4 0.70 1.0551 x 10-3 Hint: You will need to fit this data to a least-squares line, which can be done most easily in either Excel or in WolframAlpha. 2. The molar heat capacities for solid, liquid, and gaseous molecular chlorine can be written in the following general form, where the coefficients a, b, c and d are given in the table below. Cp° = a + bT + cT2 + dT3 T Range (in K) b (in K-1) c (in K-2) d (in K-3) a Phase 15 - 172.12 -1.545 0.1502 -0.001179 3.441 x 10-6 solid 172.12-239.0 7.689 0.005582 - 1.954 x 104 liquid > 239.0 3.812 0.001220 -4.856 x 10-7
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