1. Water shows the following vibrations:A₁ symmetrical stretch at 3657 cm ¹, B2 asymmetrical stretch at 3756 cm ¹,A₁ deformation at 1595 cm ¹¹.Determine which vibrations are active in IR absorption spectra and which are active inRaman spectra.

Given that, the vibrations band of water are shown below A1 symmetrical strech at 3657 cm-1. B2…

1. Water shows the following vibrations: A₁ symmetrical stretch at 3657 cm¹, B2 asymmetrical stretch at 3756 cm ¹, A₁ deformation at 1595 cm ¹1. Determine which vibrations are active in IR absorption spectra and which are active in Raman spectra.

1. Water shows the following vibrations: A₁ symmetrical stretch at 3657 cm¹, B2 asymmetrical stretch at 3756 cm ¹, A₁ deformation at 1595 cm ¹1. Determine which vibrations are active in IR absorption spectra and which are active in Raman spectra.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter14: Rotational And Vibrational Spectroscopy

Section: Chapter Questions

Problem 14.61E

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Question

1. Water shows the following vibrations:
A₁ symmetrical stretch at 3657 cm ¹, B2 asymmetrical stretch at 3756 cm ¹,
A₁ deformation at 1595 cm ¹¹.
Determine which vibrations are active in IR absorption spectra and which are active in
Raman spectra.

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