1.1 Fill in the missing (correct) words only: (a) In general, as and as increases. increases, non-ideal behavior increases decreases, non-ideal behavior (b) For an ideal gas, all virial coefficients are zero and equation reduces to (c) For real gas, virial coefficients a _dependent. are_ (d) The theorem of corresponding states (or principle of corresponding states) indicates that all fluids, when compared at the same reduced temperature and reduced pressure, have approximately the same gas behavior to about the same degree. and all deviate from ideal

1.1 Fill in the missing (correct) words only: (a) In general, as and as increases. increases, non-ideal behavior increases decreases, non-ideal behavior (b) For an ideal gas, all virial coefficients are zero and equation reduces to (c) For real gas, virial coefficients a _dependent. are_ (d) The theorem of corresponding states (or principle of corresponding states) indicates that all fluids, when compared at the same reduced temperature and reduced pressure, have approximately the same gas behavior to about the same degree. and all deviate from ideal

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter12: Thermodynamic Processes And Thermochemistry

Section: Chapter Questions

Problem 81AP

See similar textbooks

Similar questions

For ideal gases with each of the following sets of P, V, n, and T, determine the missing number. Note that these different sets of numbers are not related to one another. Pay attention to the units. PS: Make sure that you have rearranged the equation properly. If you start from the PV=nRT form of the equation, you should never have to do anything other than dividing to isolate the variable of interest. Also, make sure you are using the proper value of R. To do so, make sure the units line up with the data that is given in the question.
Define the concept of Ideal Gad & also discuss the Multiplicity of a Monatomic Ideal Gas ?
For an ideal gas P= nRT/V, and for a gas whose molecules have volume P=nRT/(V-nb) How would you modify this latter equation for a real gas to correct for the fact that there are attractive forces between molecules.
Natural gas is very abundant in many Middle Eastern oilfields. However, the costs of shipping the gas to markets inother parts of the world are high because it is necessary toliquefy the gas, which is mainly methane and has a boilingpoint at atmospheric pressure of -164 °C. One possiblestrategy is to oxidize the methane to methanol, CH3OH,which has a boiling point of 65 °C and can therefore beshipped more readily. Suppose that 10.7 * 109 ft3 of methaneat atmospheric pressure and 25 °C is oxidized to methanol.(a) What volume of methanol is formed if the densityof CH3OH is 0.791 g>mL? (b) Write balanced chemicalequations for the oxidations of methane and methanol toCO21g2 and H2O1l2. Calculate the total enthalpy changefor complete combustion of the 10.7 * 109 ft3 of methanejust described and for complete combustion of the equivalentamount of methanol, as calculated in part (a).(c) Methane, when liquefied, has a density of 0.466 g>mL;the density of methanol at 25 °C is 0.791…
Natural gas is very abundant in many Middle Eastern oilfields. However, the costs of shipping the gas to markets inother parts of the world are high because it is necessary toliquefy the gas, which is mainly methane and has a boilingpoint at atmospheric pressure of -164 °C. One possiblestrategy is to oxidize the methane to methanol, CH3OH,which has a boiling point of 65 °C and can therefore beshipped more readily. Suppose that 10.7 x 109 ft3 of methaneat atmospheric pressure and 25 °C is oxidized to methanol.(a) What volume of methanol is formed if the densityof CH3OH is 0.791 g/mL? (b) Write balanced chemicalequations for the oxidations of methane and methanol toCO2(g) and H2O(l). Calculate the total enthalpy changefor complete combustion of the 10.7 x 109 ft3 of methane just described and for complete combustion of the equivalentamount of methanol, as calculated in part (a).(c) Methane, when liquefied, has a density of 0.466 g/mL;the density of methanol at 25 °C is 0.791 g/mL.…
It can be useful to approximate the behavior of real gases. Imagine you find a gasapproximately obeys the equation of state p(Vm − b) = RT and that you decrease the volume.Based on this equation of state, would it be possible to liquefy this gas? Would you predict a gasbehaving this way has a critical temperature? Explain.
Expla in how the experiments of Boyle, Charles, andAvogadro led to the formulation of the perfect gas equation of state.
Real concepts has always proved to be complex in nature, a student after goingthrough Vander Waal’s equation was baffled to know the answers to the following questions: - Why is the term that corrects for volume, negative and the term that corrects forpressure is positive in van der Waals equation?
What Is The Ideal-Gas Equation of State?
Give a simple, intuitive, very short and non-mathematical explanation of why Cp,mof an ideal gas is bigger than CV,m.
Find expressions for α and κ for a solid obeying the following equation of state: V = nc1 + nc2P + nc3T + nc4P2 – nc5PT Given that V is volume, P is pressure, T is temperature, n is number of moles, and c1, c2, c3, c4, and c5 are constants.
An experiment in the analysis of magnesium ribbon illustrates the use of Ideal Gas Law. The number of moles of the gas produced can be calculated from the experimental data of pressure, volume and temperature. If the experiment was repeated with the same mass of Fe(s) instead of Mg(s), and all others parameters constant, the calculated ngas will _______. A. indeterminateB. increaseC. decrease